Bisabolene Fuel Conversion for Navy Range

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Solution Overview

Problem

Current fuel technologies for Navy platforms rely on nonsustainable petroleum sources, leading to high carbon emissions and limited range and loiter time for aircraft and weapon systems.

Innovation Solution

Conversion of sesquiterpenes, specifically alpha-bisabolene, into high-density fuels through fermentation, catalytic isomerization, and hydrogenation, which can be blended with other fuels to achieve higher net heat of combustion and cetane numbers, reducing carbon footprint and improving performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional petroleum-based fuels are used, then current fuel technologies are available, but carbon emissions are high and range/loiter time are limited

Engineering Contradiction:
Improvecarbon emissionsVSAvoidrange and loiter time
Core Design Contradiction:
Object-affected harmful factorsVSDuration of action of moving object

Solution Approach 1:

The patent changes the chemical composition parameters of the fuel by converting sesquiterpenes through catalytic isomerization and hydrogenation to produce hydrocarbons with specific molecular structures (C10-C16 range) that achieve superior energy density and combustion properties, thereby reducing carbon emissions while extending range and loiter time

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces petroleum-based fuel production with a biological conversion process using sesquiterpenes from renewable sources, substituting the mechanical extraction and refining of petroleum with biochemical fermentation and catalytic conversion processes that produce cleaner-burning fuels

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Use of energy by moving object

If sesquiterpenes are converted through fermentation, catalytic isomerization, and hydrogenation, then high-density fuels with higher net heat of combustion are produced, but the conversion process complexity increases

Engineering Contradiction:
Improvenet heat of combustionVSAvoidconversion process complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent segments the fuel conversion process into three distinct stages: (1) fermentation of sesquiterpenes to produce precursor compounds, (2) catalytic isomerization to rearrange molecular structures, and (3) hydrogenation to saturate bonds and form final hydrocarbon products. This segmentation allows each process to be optimized independently while maintaining overall efficiency

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses catalysts as intermediaries in the conversion process, where catalytic agents facilitate the isomerization and hydrogenation reactions without being consumed, enabling the transformation of sesquiterpenes into high-energy hydrocarbons with controlled complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If fuels are blended to achieve higher cetane numbers, then combustion performance improves, but the fuel formulation complexity increases

Engineering Contradiction:
Improvecombustion performanceVSAvoidfuel formulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent creates composite fuel formulations by blending converted sesquiterpene hydrocarbons with other fuel components in specific ratios to achieve target cetane numbers and combustion characteristics, combining the advantages of different hydrocarbon structures to optimize performance

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting fuels offer increased range and loiter time for Navy platforms while decreasing reliance on petroleum and lowering carbon emissions, with properties comparable to or exceeding those of JP-10 and JP-5 fuels.

Implementation Method 1

Fuels derived from bisabolene can have volumetric net heats of combustion comparable to JP-10 and can be produced from biomass sugars

Methodology Applied
Scientific EffectFermentation: Fermentation

Implementation Method 2

bisabolene has three alkene groups which can be catalytically isomerized to generate fuels with net heats of combustion higher than JP-10

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

The product mixture is hydrogenated to yield a saturated mixture

Methodology Applied
Scientific EffectHydrogenation: Hydrogenation

Data Source

PatentUS10053643B1Fuels and lubricants from bisaboline
Publication Date: 2018.08.21 THE GOVERNMENT OF THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY DEPARTMENT OF HEALTH & HUMAN SERVICES
  • US10053643B1 patent drawing
  • US10053643B1 patent drawing
  • US10053643B1 patent drawing

AI summary

A process for making high density fuels having the potential to increase the range and/or loiter time of Navy platforms. Derivation of these fuels from a sustainable source will decrease the carbon footprint of the Department of Defense (DoD) and reduce reliance on nonsustainable petroleum sources. Fuels derived from bisabolene can have volumetric net heats of combustion comparable to JP-10 and can be produced from biomass sugars.