Bisindenofluorene Compounds for Blue OLED Lifetime and Color

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Solution Overview

Problem

Current organic electronic devices, particularly OLEDs, face challenges in achieving long lifetime, low operating voltage, high power efficiency, and suitable color coordinates, especially for blue-emitting devices, with existing compounds.

Innovation Solution

Development of novel compounds with a bisindenofluorene basic structure, specifically formulated to enhance performance in emitting layers, offering deep-blue color coordinates and improved operational parameters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If conventional compounds are used in OLEDs, then device structure and prior art requirements are met, but lifetime and color coordinates for blue-emitting devices are insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoidcolor coordinates performance
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent modifies molecular parameters by introducing specific substituents (Ar1, Ar2, X1, R1-R5) at defined positions on the indenofluorene core structure. This systematic parameter variation optimizes both lifetime and color coordinates, resolving the contradiction between durability and optical performance in blue-emitting OLEDs

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite molecular structures by combining indenofluorene basic structure with various aromatic substituents (Ar1, Ar2) and functional groups (X1). This composite approach enables simultaneous achievement of long device lifetime and appropriate color coordinates that cannot be obtained with single-structure compounds

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If existing compounds are used, then commercial availability and ease of manufacture are maintained, but operating voltage and power efficiency are insufficient

Engineering Contradiction:
Improvecompound availabilityVSAvoidoperating voltage
Core Design Contradiction:
Ease of manufactureVSUse of energy by stationary object

Solution Approach 1:

The patent optimizes energy parameters by adjusting molecular structure (Ar1, Ar2, X1 substitutions) to achieve lower operating voltages and improved power efficiency. These parameter modifications maintain manufacturability while significantly improving electrical performance metrics

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If blue-emitting compounds are used, then deep-blue color coordinates are achieved, but lifetime is reduced

Engineering Contradiction:
Improvecolor coordinatesVSAvoiddevice lifetime
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The invention develops composite molecular structures combining indenofluorene with specific aromatic substituents that simultaneously provide deep-blue emission characteristics and enhanced stability. This composite approach breaks the traditional trade-off between color performance and device lifetime in blue OLEDs

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS10559756B2Materials for electronic devices
Publication Date: 2020.02.11 MERCK PATENT GMBH
  • US10559756B2 patent drawing
  • US10559756B2 patent drawing
  • US10559756B2 patent drawing

AI summary

The invention relates to compounds with benzindenofluorene base bodies having a structure of formula (I):and to the use thereof in electronic devices, in particular in organic electroluminescent devices.