Bismuth Carboxylate Markers for Solid Wood Authentication

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Solution Overview

Problem

There is a need for a durable and practical method to mark and authenticate wood products that are not pulped, extruded, or woven, as existing methods are not suitable for lumber and do not withstand exposure to the elements.

Innovation Solution

The use of carboxylates dispersed in water or an aqueous solution, specifically bismuth carboxylates, as markers that are compatible with wood treatment processes, allowing for detection by x-ray fluorescence or plasma emission analysis, which can be integrated into wood products during pressure-treating cycles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If existing marking methods (rare earth chelates in paper, fluorescent dyes in pulped wood) are used, then paper or pulped wood products can be authenticated, but these methods are not practical for solid lumber that is not pulped, extruded, or woven

Engineering Contradiction:
Improveapplicability to solid lumberVSAvoidprocess complexity
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The invention changes the physical state parameter of the marking agent from requiring pulped/extruded forms to working with solid lumber in its natural state. The fluorescent marker is applied as a surface coating or injection into solid wood, eliminating the need for pulping or extrusion processes while achieving durable authentication marking on commercial lumber products.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention extracts the fluorescent marking function from the complex papermaking or extrusion processes and applies it directly to solid lumber surfaces or interiors through simpler coating or injection methods, separating the authentication capability from the structural formation process.

Inventive Principle:
Principle #2Taking out (Extraction)

2Ease of manufacture

If markers are placed on the surface of wood products, then marking is simple, but the markers are exposed to the elements and not protected

Engineering Contradiction:
Improvemarking simplicityVSAvoidmarker durability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The fluorescent marker is nested within the wood product structure itself, either embedded in the cellular structure through vacuum pressure treatment or incorporated into protective coatings that form part of the wood's outer layer. This nesting protects the marker from environmental exposure while maintaining the simplicity of the marking process.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The invention uses thin film coatings or surface treatments that encapsulate the fluorescent marker, creating a protective layer that shields the marker from weathering, UV exposure, and microbial attack while allowing the marker to remain detectable through fluorescence analysis.

Inventive Principle:
Principle #30Flexible shells and thin films

3Reliability

If wood is treated with pressure-vacuum cycles to force treating solutions into wood fibers, then resistance to weathering and decay is increased, but it is difficult to determine where and how the wood was treated and by whom

Engineering Contradiction:
Improveweathering resistanceVSAvoidtreatment identification
Core Design Contradiction:
ReliabilityVSLoss of information

Solution Approach 1:

The invention merges the protective treating solution with a fluorescent marker component, so that the same pressure-vacuum treatment process that forces preservative chemicals into the wood also embeds the authentication marker. This combination ensures both weathering resistance and treatment identification are achieved through a single integrated process.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The fluorescent marker serves dual functions: it provides authentication information about the treatment source and simultaneously acts as a traceable identifier that survives the weathering conditions. The marker essentially identifies itself and the treatment process through its fluorescent properties, eliminating the need for separate identification systems.

Inventive Principle:
Principle #25Self-service

4Measurement precision

If fluorescent markers are used in wood products, then detection is enabled, but the markers must be compatible with wood treatment processes and resistant to weathering and microbial attack

Engineering Contradiction:
Improvedetection capabilityVSAvoidcompatibility with treatment processes
Core Design Contradiction:
Measurement precisionVSAdaptability or versatility

Solution Approach 1:

The fluorescent marker is formulated as a composite material that combines fluorescent compounds with wood-compatible carriers or encapsulants. This composite structure allows the marker to withstand the chemical environment of pressure-vacuum treating processes, resist microbial degradation, and maintain fluorescent detectability under various weathering conditions.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method provides a durable and detectable marker that is resistant to weathering and microbial attack, enabling reliable identification of wood products using non-destructive or destructive analytical methods.

Implementation Method 1

Pressure-vacuum cycles are commonly utilized to force the treating solutions between and into wood fibers

Methodology Applied
Scientific EffectPressure-vacuum cycles: Pressure Increase

Implementation Method 2

The metal may be fluorescent when excited by x-ray radiation

Methodology Applied
Scientific EffectX-ray fluorescence: Fluorescence

Data Source

PatentEP3387078B1Wood marking and identification
Publication Date: 2025.01.15 TROY CORP

AI summary

Wood markers and processes for durably marking and subsequently identifying both original grain wood products and wood-plastic composite products. The wood marker can be dispersed beneath the surface of the wood, where it is protected from the elements and may endure years of exposure to the elements. The wood marker is compatible with state-of-the-art pressure-treating processes and may subsequently be detected for authentication purposes by known analytical methods.