Bismuth Halide-PDMS Composite for Lightweight X-Ray Shielding

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Solution Overview

Problem

Existing lead-based X-ray shielding materials face issues such as environmental hazards, human toxicity, poor fit, and heavy weight, with challenges in material dispersion and weight reduction remaining unsolved in alternative solutions.

Innovation Solution

A method involving the production of a bismuth halide compound-PDMS composite material, where porous PDMS is loaded with bismuth halides like BiI3, BiBr3, and BiCl3, enhancing X-ray shielding performance through uniform distribution and complexation, resulting in a lightweight and flexible alternative.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If lead-based materials are used for X-ray shielding, then excellent shielding performance is achieved, but environmental hazards and human toxicity occur

Engineering Contradiction:
ImproveX-ray shielding performanceVSAvoidenvironmental hazards and human toxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces toxic lead-based materials with bismuth halide compound-PDMS composite materials that offer comparable shielding performance without environmental hazards. The composite uses biocompatible PDMS as a polymer matrix and bismuth halide compounds as shielding agents, eliminating the harmful effects of lead while maintaining protective functionality against X-rays.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention creates a composite material system combining PDMS (polymer matrix) with bismuth halide compounds (shielding agents). This composite structure integrates the flexibility and biocompatibility of PDMS with the high X-ray attenuation capability of bismuth halides, achieving both excellent shielding performance and environmental safety.

Inventive Principle:
Principle #40Composite materials

2Reliability

If lead-based shielding materials are used, then effective radiation protection is provided, but heavy weight is incurred

Engineering Contradiction:
Improveradiation protectionVSAvoidshielding material weight
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The patent modifies the density and composition parameters by using bismuth halide compounds with lower density compared to lead, while maintaining effective X-ray attenuation through optimized concentration and distribution within the PDMS matrix. This parameter optimization reduces material weight while preserving radiation protection capability.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If traditional shielding materials are replaced with alternative materials, then environmental safety is improved, but poor material dispersion occurs

Engineering Contradiction:
Improveenvironmental safetyVSAvoidmaterial dispersion uniformity
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent utilizes the porous structure of PDMS to enhance the dispersion and distribution of bismuth halide compounds. The porous matrix provides extensive surface area and pathways for uniform distribution of shielding agents, preventing aggregation and ensuring homogeneous composition throughout the composite material.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The PDMS polymer acts as an intermediary medium that facilitates uniform dispersion of bismuth halide compounds. The polymer matrix provides a compatible environment that prevents direct aggregation of bismuth halide particles, ensuring stable and homogeneous distribution of the shielding agents within the composite structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If conventional shielding materials are used, then radiation protection is achieved, but poor flexibility and fit are incurred

Engineering Contradiction:
Improveradiation protectionVSAvoidflexibility and fit
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent employs PDMS as a flexible polymer matrix that can be formed into thin, conformable films or shells. This flexible composite structure can adapt to various body contours and device surfaces, providing excellent fit and comfort while maintaining effective X-ray shielding performance through the distributed bismuth halide compounds.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material achieves improved X-ray shielding efficacy, allowing for lightweight, flexible radiation shielding solutions suitable for diverse industries, including medical, aerospace, and electronic devices, with minimal environmental and health risks.

Implementation Method 1

a third step of immersing the porous PDMS into the mixed solution such that the bismuth halide compound is loaded into the porous PDMS

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

a material using a Bi (bismuth) halide (BiI3, BiBr3, BiCl3, BiF3) compound and PDMS was developed... the bismuth halides are mixed with each other at an appropriate ratio to produce a shielding material that has improved X-ray shielding ability

Methodology Applied
Scientific EffectPhotoelectric absorption: Absorption (EM radiation)

Data Source

PatentUS12580090B2Bismuth halide compound-PDMS composite material for X-ray shielding and manufacturing method thereof
Publication Date: 2026.03.17 PUKYONG NAT UNIV IND ACADEMIC COOPERATION FOUND
  • US12580090B2 patent drawing
  • US12580090B2 patent drawing
  • US12580090B2 patent drawing

AI summary

A method for producing a lead-free X-ray shielding material using a bismuth halide compound is provided, the method including a first step of producing porous PDMS (Polydimethylsiloxane); a second step of producing a mixed solution of the bismuth halide compound and THF; and a third step of immersing the porous PDMS into the mixed solution such that the bismuth halide compound is loaded into the porous PDMS to produce a bismuth halide compound-PDMS composite material.