Bisphenol A Markers for Fuel Digital Coding

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Solution Overview

Problem

There is a need for additional marker compounds to enhance the digital marking systems for liquid hydrocarbons and other fuels, as existing markers may not provide sufficient coding capacity or detectability.

Innovation Solution

The method involves adding specific compounds with the formula (I) to petroleum hydrocarbons or biologically derived fuels, where R1 and R2 are hydrogen or C1-C4 alkyl groups, and G represents hydrogen or C1-C18 alkyl and alkoxy substituents, to create unique markers that can be detected using chromatographic techniques and mass spectral analysis, allowing for coded identification.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If additional marker compounds are introduced to enhance digital marking systems, then the coding capacity and detection capabilities are improved, but the complexity of the marking system increases

Engineering Contradiction:
Improvecoding capacityVSAvoidsystem complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent introduces multiple distinct marker compounds (compounds of formula I with different R1, R2, and G substituents) that can be used in combination to form digital marking codes. Each compound acts as a separate element that can be selectively added to fuels, allowing for multiple code combinations without requiring a single complex marker system.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent utilizes variations in chemical parameters (substituents R1, R2, and G on the bisphenol A core structure) to create distinct marker compounds. By changing these chemical parameters, different markers are generated that can be detected through mass spectrometry or other analytical techniques, enabling digital coding capacity while maintaining individual compound simplicity.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If multiple marker compounds are used to form digital codes, then the detection capability and identification accuracy are improved, but the difficulty of detecting and measuring increases

Engineering Contradiction:
Improvedetection capabilityVSAvoidmeasurement difficulty
Core Design Contradiction:
Measurement precisionVSDifficulty of detecting and measuring

Solution Approach 1:

The patent replaces complex multi-parameter measurement systems with mass spectrometry or other analytical techniques that can selectively detect and quantify specific marker compounds based on their unique mass-to-charge ratios or other detectable properties. This substitution simplifies the measurement process while maintaining high precision for detecting multiple markers simultaneously.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Data Source

PatentUS9005315B2Bisphenol A compounds as markers for liquid hydrocarbons and other fuels and oils
Publication Date: 2015.04.14 ROHM & HAAS CO
  • US9005315B2 patent drawing
  • US9005315B2 patent drawing
  • US9005315B2 patent drawing

AI summary

A method for marking a petroleum hydrocarbon or a liquid biologically derived fuel by adding at least one compound having formula (I),wherein R1 and R2 independently represent hydrogen or C1-C4 alkyl groups, and G represents hydrogen or at least one substituent selected from the group consisting of C1-C18 alkyl and C1-C18 alkoxy.