Anti-Aging Additives for Bitumen Aging Delay

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Solution Overview

Problem

Bitumen aging leads to reduced mechanical performance and lifespan of road surfaces, particularly due to increased asphaltene content, which results in cracking and loss of sealing integrity, necessitating the development of additives to delay aging and improve longevity.

Innovation Solution

The use of specific anti-aging additives, such as compounds of formula (1) and (2), in concentrations between 0.01% and 10% by weight, which include alkylene oxide-based polymers and amidoamine derivatives, are added to bitumen to slow down degradation and extend its lifespan, both in new and recycled bituminous materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If bitumen is used in road construction without additives, then initial mechanical performance is achieved, but aging occurs leading to cracking and loss of sealing integrity over time

Engineering Contradiction:
Improvesealing integrityVSAvoidlifespan
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent applies preliminary action by adding anti-aging additives to bitumen before it is used in road construction. These additives prevent aging-related degradation from occurring in the first place, rather than treating it after cracking appears. The additives are incorporated into the bitumen mix during production, ensuring protective action is already in place before the road is laid, thereby extending lifespan while maintaining sealing integrity.

Inventive Principle:
Principle #10Preliminary action

2Ease of repair

If bitumen is heated for recycling, then degraded bituminous material can be returned to appropriate form, but additional degradation occurs during heating

Engineering Contradiction:
ImproverecyclabilityVSAvoidmechanical performance
Core Design Contradiction:
Ease of repairVSReliability

Solution Approach 1:

The patent applies beforehand cushioning by incorporating anti-aging additives that provide protective action before thermal degradation can occur during recycling. These additives cushion against the harmful effects of high-temperature heating, preventing additional degradation that would normally occur during the recycling process. This allows bitumen to be recycled multiple times while maintaining mechanical performance and reliability.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Strength

If asphaltene content increases due to aging, then bitumen hardens, but this leads to cracking and degraded properties

Engineering Contradiction:
ImprovehardnessVSAvoidcrack resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies blessing in disguise by using anti-aging additives that interfere with the aging process itself. Instead of accepting increased asphaltene content as an inevitable consequence leading to cracking, the additives prevent the chemical reactions that cause asphaltene precipitation and aggregation. This converts the potential harm of aging into a benefit by maintaining the original balanced composition, thereby preserving both appropriate hardness and crack resistance simultaneously.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Data Source

PatentUS20230072410A1Use of an additive to delay bitumen ageing
Publication Date: 2023.03.09 ARKEMA FRANCE SA
  • US20230072410A1 patent drawing
  • US20230072410A1 patent drawing
  • US20230072410A1 patent drawing

AI summary

The invention relates to the use of an additive chosen from the compounds of formula (1) and the compounds of formula (2) as follows: in which A, B, E, Y, Z and d and j are as defined in the description, the anti-ageing additive being present in an amount of between 0.01% and 10% by weight, relative to the total weight of the bituminous product, in order to delay the ageing of the bitumen. The invention also relates to a composition comprising:—a bituminous product,—at least one anti-ageing additive as described above, and—at least one anti-oxidant agent, the anti-ageing additive being present in an amount of between 0.01% and 10% by weight, relative to the total weight of the bituminous product.