Bituminous Emulsions Additives Fluidity Cohesion

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Solution Overview

Problem

Current bituminous coating processes at temperatures above 100°C consume significant fossil fuels, produce greenhouse gases, and have limitations in mechanical performance, especially when using non-naphthenic bitumens, while cold-cast asphalts with non-naphthenic bitumen emulsions face challenges in cohesion and durability.

Innovation Solution

Incorporating additives such as ethylene oxide-propylene oxide copolymers, phosphorus-containing compounds, and adhesiveness boosters into bituminous products to enhance fluidity and cohesion, allowing for reduced production temperatures and improved mechanical properties, thereby matching the performance of naphthenic bitumen mixes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If bituminous coating processes are conducted at temperatures above 100°C, then good coating quality and mechanical performance are achieved, but fossil fuel consumption and greenhouse gas emissions increase significantly

Engineering Contradiction:
Improvecoating qualityVSAvoidfossil fuel consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The invention changes the temperature parameter from above 100°C to between 60-100°C by modifying the bitumen composition. This parameter change allows the coating process to proceed at lower temperatures while maintaining adequate coating quality, thereby reducing fossil fuel consumption and greenhouse gas emissions associated with high-temperature heating.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite bitumen materials containing multiple additives (polymer modifiers, waxes, surfactants) combined with traditional bitumen. These composite materials modify the rheological properties of bitumen, enabling it to remain sufficiently fluid at lower temperatures (60-100°C) for effective coating, thus resolving the contradiction between temperature reduction and coating quality maintenance.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If non-naphthenic bitumen emulsions are used in cold-cast asphalts, then availability and cost are improved, but cohesion and durability at young age are insufficient

Engineering Contradiction:
Improvebitumen availabilityVSAvoidcohesion
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The invention creates composite bitumen formulations by combining non-naphthenic bitumen with specific additives including polymer modifiers (ethylene-propylene-diene copolymer, styrene-butadiene-styrene block copolymer), waxes (microcrystalline wax, polyethylene wax), and surfactants. This composite approach enhances the cohesion and durability of cold-cast asphalt at young age while maintaining the availability and cost advantages of non-naphthenic bitumen.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention modifies the chemical and physical parameters of non-naphthenic bitumen through additive incorporation. The polymer modifiers increase molecular weight and improve elastic properties, while waxes and surfactants modify surface properties and adhesion characteristics. These parameter changes enable non-naphthenic bitumen to achieve cohesion levels comparable to or exceeding traditional naphthenic bitumen in cold-cast asphalt applications.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If production temperature is reduced to decrease energy consumption, then fossil fuel consumption and emissions are reduced, but fluidity and coating performance deteriorate

Engineering Contradiction:
Improveenergy consumptionVSAvoidcoating performance
Core Design Contradiction:
Use of energy by moving objectVSObject-generated harmful factors

Solution Approach 1:

The invention employs composite bitumen materials containing polymer modifiers, waxes, and surfactants that work synergistically to maintain fluidity at reduced temperatures. The polymer modifiers provide chain flexibility, waxes control viscosity through crystallization behavior, and surfactants reduce surface tension. This composite formulation enables effective coating at 60-100°C without sacrificing coating performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the rheological parameters of bitumen through additive incorporation. The polymer modifiers alter the molecular structure to enhance flexibility at lower temperatures, waxes modify the viscosity-temperature relationship, and surfactants improve wetting properties. These parameter changes allow the bitumen to maintain adequate fluidity for coating at lower temperatures (60-100°C), resolving the contradiction between energy reduction and performance maintenance.

Inventive Principle:
Principle #35Parameter changes

4Adaptability or versatility

If non-naphthenic bitumen is used instead of naphthenic bitumen, then availability and cost are improved, but fluidity and mechanical performance are reduced

Engineering Contradiction:
Improvebitumen availabilityVSAvoidmechanical performance
Core Design Contradiction:
Adaptability or versatilityVSObject-generated harmful factors

Solution Approach 1:

The invention formulates composite bitumen materials by combining non-naphthenic bitumen with polymer modifiers (ethylene-propylene-diene copolymer, styrene-butadiene-styrene block copolymer), waxes, and surfactants. These composite materials compensate for the inherently lower fluidity and mechanical performance of non-naphthenic bitumen, achieving performance levels comparable to or exceeding traditional naphthenic bitumen while maintaining availability and cost advantages.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention modifies the chemical and physical parameters of non-naphthenic bitumen through systematic additive incorporation. Polymer modifiers increase molecular weight and improve elastic recovery, waxes adjust viscosity and melting behavior, and surfactants enhance adhesion properties. These parameter changes transform non-naphthenic bitumen into a high-performance material that matches or exceeds traditional naphthenic bitumen in mechanical performance while maintaining availability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these additives reduces fossil fuel consumption, decreases greenhouse gas emissions, and enhances the mechanical properties of bituminous mixes, improving cohesion and durability, while maintaining process manageability and adhering to industry standards.

Implementation Method 1

Incorporating additives such as ethylene oxide-propylene oxide copolymers, phosphorus-containing compounds, and adhesiveness boosters into bituminous products to enhance fluidity

Methodology Applied
Scientific EffectViscosity reduction through polymer additive:

Implementation Method 2

This development involves the coalescence of the bitumen in the emulsion, a coalescence which strongly depends on the quality of the bitumen

Methodology Applied
Scientific EffectCoalescence: Coagulation

Implementation Method 3

adhesiveness boosters into bituminous products to enhance fluidity and cohesion

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP2035504B1Bituminous products and aqueous emulsions based on bituminous products and uses thereof
Publication Date: 2021.04.14 ARKEMA FRANCE SA
  • EP2035504B1 patent drawing
  • EP2035504B1 patent drawing
  • EP2035504B1 patent drawing

AI summary

The invention concerns novel bituminous products, as well as novel aqueous emulsions of bituminous products, mixtures thereof with coated granules, useful for sealing applications, building and maintaining road surfaces, sidewalks and runways, road surfaces, sidewalks, bicycle paths, parking lots and runways.