Black Titanium Dioxide Nonstick Coating for Wear-Resistant Cookware

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Solution Overview

Problem

Existing nonstick pans face issues with poor temperature resistance, susceptibility to scratching or breaking, and short service life due to brittle coatings, which limit their nonstick performance and require protective spatulas, hindering a better cooking experience.

Innovation Solution

A nonstick pan with a substrate coated with a layer of black titanium dioxide, optionally combined with other ceramics or metals, applied using hot spraying or solid-phase sintering, providing a durable and effective nonstick surface with low surface energy characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If fluororesin coating is used to achieve nonstickness, then nonstick performance is improved, but wear resistance deteriorates and service life is shortened

Engineering Contradiction:
Improvenonstick performanceVSAvoidwear resistance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent uses a composite coating structure consisting of a fluororesin nonstick layer combined with a ceramic base layer. The ceramic layer provides hardness and wear resistance, while the fluororesin layer provides nonstick performance. This composite structure resolves the contradiction by combining materials with complementary properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The coating is designed with different layers having different properties: the ceramic base layer provides mechanical strength and wear resistance, while the fluororesin surface layer provides low surface energy for nonstick performance. Each layer is optimized for its specific function, resolving the contradiction between nonstick performance and durability.

Inventive Principle:
Principle #3Local quality

2Reliability

If coating thickness is increased to improve durability, then wear resistance is improved, but coating cracking occurs during sintering

Engineering Contradiction:
Improvecoating durabilityVSAvoidcoating integrity
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The coating is divided into multiple layers with different thicknesses and functions. The ceramic base layer provides thickness and durability, while the fluororesin surface layer remains thin enough to avoid cracking during sintering. This segmentation allows each layer to be optimized independently, resolving the contradiction between durability and integrity.

Inventive Principle:
Principle #1Segmentation

3Reliability

If ceramic coating is used to improve hardness, then wear resistance is improved, but nonstick performance deteriorates under high temperature and friction

Engineering Contradiction:
ImprovehardnessVSAvoidnonstick performance stability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent combines ceramic material for hardness with fluororesin material for stable nonstick performance. The fluororesin layer maintains its low surface energy properties even under high temperature and friction conditions, while the ceramic layer provides the necessary mechanical strength.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The surface layer is specifically designed with fluororesin material that maintains its nonstick properties under cooking conditions, while the underlying ceramic layer provides mechanical support. This local optimization of material properties resolves the contradiction between hardness and nonstick stability.

Inventive Principle:
Principle #3Local quality

4Reliability

If protective spatulas are used to prevent coating damage, then coating durability is improved, but cooking experience deteriorates

Engineering Contradiction:
Improvecoating protectionVSAvoidcooking experience
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The composite coating structure with ceramic base layer and fluororesin surface layer achieves such high durability that metal spatulas can be used without damaging the coating. This eliminates the need for protective wooden or plastic spatulas, improving cooking experience while maintaining coating protection.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The black titanium dioxide coating enhances nonstick performance, durability, and resistance to wear, extending the life of the nonstick layer while allowing for use with metal spatulas, improving cooking experience and usability.

Implementation Method 1

achieve the nonstickness by means of their low surface energy of a fluororesin

Methodology Applied
Scientific EffectLow surface energy: Surface Tension

Implementation Method 2

applied using hot spraying or solid-phase sintering

Methodology Applied
Scientific EffectHot spraying: Plasma Spray

Implementation Method 3

applied using hot spraying or solid-phase sintering

Methodology Applied
Scientific EffectSolid-phase sintering: Sintering

Implementation Method 4

they have poor wear resistance, resulting in a short service life

Methodology Applied
Scientific EffectWear resistance: Wear

Data Source

PatentEP3683330A1Nonstick utensil and manufacturing method thereof
Publication Date: 2020.07.22 WUHAN SUPOR COOKWARE
  • EP3683330A1 patent drawingFigure 1~3
  • EP3683330A1 patent drawingFigure 4~5
  • EP3683330A1 patent drawingFigure 6

AI summary

The present invention relates to the technical field of cooking utensils, and in particular, to a nonstick utensil and its method of manufacturing. The nonstick utensil comprises a utensil substrate and a nonstick layer covering an inner surface of the utensil substrate; the material of the nonstick layer comprises black titanium dioxide. In these method of the present invention, an inner surface of a substrate of the nonstick utensil is covered with a material comprising black titanium dioxide by means of hot spraying, cold spraying or plasma spraying, so that a black titanium dioxide nonstick layer is formed. Compared to the prior art, instead of using a coating material, the present invention achieves the objective of nonstickness by forming nonstick layer comprising black titanium dioxide on a surface of a substrate, thanks to the low surface energy characteristic of black titanium dioxide.