Black Toner Resolving Fusing and Gloss Trade-Off via Silane Mediator

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Solution Overview

Problem

Black toners often exhibit low gloss and poor fusing performance due to their conductive nature, which affects their usability in electrophotographic devices and inkjet printing.

Innovation Solution

A black single-component toner formulation comprising a styrene/acrylate resin, a black colorant, a cyan colorant, low melt wax, and surface additives like hydrophobic silica and lubricants, which enhances compressibility, flowability, and fusing performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If black colorant is used in toner, then color density and blackness degree are improved, but gloss and fusing performance deteriorate

Engineering Contradiction:
Improvecolor densityVSAvoidfusing performance
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

A silane-modified polymer intermediary is introduced to bridge the black colorant particles and the toner matrix. This intermediary has dual functionality: it compatibilizes with the black colorant to maintain color density while also being compatible with the toner resin matrix to restore gloss and fusing performance. The silane-modified polymer acts as a molecular bridge that resolves the conflict between color intensity and fusing capability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The toner composition is formulated as a composite material system combining black colorant, silane-modified polymer, and toner resin in specific ratios. This composite approach allows the system to simultaneously achieve high color density from the black pigment while the polymer matrix and silane modifier restore the gloss and fusing properties that would otherwise be compromised by the conductive black colorant.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If black colorant is used in toner, then blackness degree is improved, but surface gloss deteriorates

Engineering Contradiction:
Improveblackness degreeVSAvoidsurface gloss
Core Design Contradiction:
Illumination intensityVSShape

Solution Approach 1:

The silane-modified polymer serves as a surface-active intermediary that migrates to the toner particle surface, forming a glossy coating layer. This surface layer restores light reflection properties (gloss) while the underlying black colorant maintains high blackness degree. The intermediary effectively decouples surface optical properties from bulk color properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The toner particle exhibits local quality differentiation: the surface region contains higher concentration of silane-modified polymer providing gloss, while the core region maintains high black colorant concentration for blackness. This spatial separation of functions allows simultaneous optimization of both surface gloss and bulk blackness degree.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The toner achieves improved gloss and fusing performance by effectively adhering additives to the surface, reducing toner build-up, and optimizing particle size and shape, resulting in enhanced imaging device capabilities.

Implementation Method 1

a hydrophobic silica

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 2

a lubricant

Methodology Applied
Scientific EffectLubrication: Lubrication

Implementation Method 3

a low melt wax

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS8852835B2Black toner
Publication Date: 2014.10.07 XEROX CORP

AI summary

The present disclosure describes a black single component toner with desirable fusing performance.