Blended Polymer Laser Composition for Broad Wavelength Tuning

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current solid-state laser systems are limited in producing tunable laser emission across a broad wavelength range, particularly from blue to infrared, which is necessary for applications like health monitoring, environmental monitoring, and tissue imaging, as they typically operate at a single wavelength and require complex feedback structure designs.

Innovation Solution

A solid-state blended polymer system using a blend of poly(9,9-dioctylfluorene) (PFO), poly(2-(2′,5′-bis(2″-ethylhexyloxy)phenyl)-1,4-phenylenevinylene) (BEHP-PPV), and poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (MEH-PPV) polymers, where the blending ratio is adjusted to achieve tunable lasing wavelengths by integrating a DFB feedback structure with varying grating periods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If a single organic polymer system is used for laser emission, then the device complexity is reduced, but the tunable wavelength range is limited

Engineering Contradiction:
Improvetunable wavelength rangeVSAvoidpolymer blend composition
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent uses composite polymer blends combining PFO and MEH-PPV polymers to achieve broad tunable wavelength range (blue to red) while maintaining relatively simple device structure. The composite material approach allows spectral coverage that single polymers cannot provide alone.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The blended polymer system serves multiple functions: PFO provides blue emission region, MEH-PPV provides red emission region, and together they cover the entire visible spectrum from blue to red, making a single system universally applicable for multi-wavelength applications.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Adaptability or versatility

If feedback structure design is used to achieve tunable laser emission, then the lasing wavelength can be tuned, but the device complexity and production cost increase

Engineering Contradiction:
Improvelasing wavelength tuningVSAvoidfeedback structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent achieves wavelength tuning by changing the composition parameter (blending ratio) of the polymer blend rather than modifying feedback structures. By adjusting the ratio of PFO to MEH-PPV, the emission wavelength can be tuned across the visible spectrum, simplifying the device design.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces mechanical/optical feedback structure adjustments with a material composition approach. Instead of tuning feedback structures to change wavelength, the wavelength is determined by the chemical composition of the polymer blend, substituting a material science solution for an optical engineering solution.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Adaptability or versatility

If multiple separate laser systems are used to cover broad wavelength range, then the wavelength coverage is improved, but the production cost and system integration complexity increase

Engineering Contradiction:
Improvewavelength coverageVSAvoidsystem integration
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent merges the functions of multiple separate laser systems into a single blended polymer system. The PFO-MEH-PPV blend combines the emission capabilities of both polymers into one material system, eliminating the need for multiple separate laser devices and simplifying integration.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The blended polymer system provides universal wavelength coverage from blue to red in a single material, making it applicable for multiple sensing applications (health monitoring, environmental monitoring, tissue imaging) without requiring separate laser systems for each wavelength region.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system enables tunable lasing outputs across a wide range (blue to red) with reduced production costs and simplified design, facilitating multi-wavelength laser sensor integration for various monitoring applications.

Implementation Method 1

The lasing material when excited will first emit photoluminescence (PL), optically excited luminescence, a process called spontaneous emission.

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 2

With further excitation, the emission become stimulated emission which is commonly called lasing.

Methodology Applied
Scientific EffectStimulated emission: Laser

Implementation Method 3

integrating a DFB feedback structure with varying grating periods

Methodology Applied
Scientific EffectDiffraction grating: Diffraction Grating

Data Source

PatentUS11837842B2Tunable laser materials comprising solid-state blended polymers
Publication Date: 2023.12.05 HONG KONG BAPTIST UNIV
  • US11837842B2 patent drawing
  • US11837842B2 patent drawing
  • US11837842B2 patent drawing

AI summary

The present invention relates to a solid-state blended polymer system that has the property of tunable lasing wavelength through adjusting the blending ratio. It can be used for health monitoring, environmental monitoring sensor and tissue imaging. Current materials do not have the broad tunable range; from blue to infra-red across the optical range. By using the same two polymers, it is possible to produce laser emitting blue to red colour. It simplifies the design, eases multi-wavelength laser sensor system integration and therefore, making the production cost-effective.