Block Copolymer Directed Self-Assembly for Multi-Size Patterning

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Solution Overview

Problem

The existing methods for forming patterns using block copolymers in directed self-assembly processes are limited in creating multiple feature sizes in a single semiconductor device layer, as the feature size is determined by the material properties of the block copolymer, necessitating separate lithography processes for each size, increasing manufacturing complexity and cost.

Innovation Solution

A pattern forming method that involves forming multiple concave portions with different widths in a resist layer, followed by the deposition of a block copolymer film that phase-separates to create distinct patterns, allowing for the use of these patterns as masks to transfer desired features to underlying layers, thereby enabling the formation of patterns with different sizes using a single lithography process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If block copolymer directed self-assembly is used to form patterns, then fine pattern features smaller than the resist layer features can be achieved, but the feature size is determined by material properties rather than being arbitrary

Engineering Contradiction:
Improveminimum feature sizeVSAvoidfeature size variability
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent applies local quality by creating different concave portion widths (first concave portions with width W1, second concave portions with width W2) in the resist layer. This allows different regions to have different local geometries that guide the block copolymer self-assembly into corresponding different feature sizes, enabling spatial variation in pattern dimensions while maintaining the benefits of DSA

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent performs preliminary action by pre-forming the resist layer pattern with multiple concave portions of different widths before introducing the block copolymer. This preliminary structuring of the substrate guides the subsequent self-assembly process to produce the desired multiple feature sizes without requiring additional lithography steps

Inventive Principle:
Principle #10Preliminary action

2Adaptability or versatility

If multiple patterns with different feature sizes are formed using separate lithography processes, then arbitrary feature sizes can be achieved, but the number of manufacturing processes increases

Engineering Contradiction:
Improvefeature size variabilityVSAvoidnumber of manufacturing processes
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent merges multiple patterning functions into a single lithography process by designing the resist layer to contain multiple concave portions with different widths. This single lithography step creates a multi-functional mask that guides block copolymer self-assembly into multiple different feature sizes simultaneously, eliminating the need for separate lithography processes for each pattern size

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The resist layer pattern serves multiple functions simultaneously: it acts as a mask for fine patterning, a template for guiding block copolymer self-assembly, and a source of multiple different feature sizes. This multi-functionality allows a single process step to achieve what would traditionally require multiple specialized lithography processes

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for the efficient formation of multiple patterns with different feature sizes in a semiconductor device layer using a single lithography process, reducing manufacturing complexity and cost by leveraging the phase-separation properties of the block copolymer to create precise and varied patterns.

Implementation Method 1

forming a pattern in the BCP film by phase-separating the BCP film

Methodology Applied
Scientific EffectPhase separation: Phase Change

Implementation Method 2

a method of forming a fine pattern using directed self-assembly (DSA) of the BCP

Methodology Applied
Scientific EffectDirected self-assembly: Self-Assembly

Data Source

PatentUS10409157B2Pattern forming method
Publication Date: 2019.09.10 KIOXIA CORP
  • US10409157B2 patent drawing
  • US10409157B2 patent drawing
  • US10409157B2 patent drawing

AI summary

A pattern forming method includes forming a first film on a first layer and a second film on the first film. First and second concave portions are formed in the second film. A third film is formed in the concave portions and a fourth film comprising a polymer is formed on the third film. The fourth film can be processed to phase separate and form a pattern in at least the first opening. The pattern formed in the fourth film can be used in patterning films thereunder. A fifth film can be formed which covers the first concave portion and does not cover the second concave portion. The third film in the second concave portion and the first film under the second concave portion can be processed using the fifth film. The first layer can be patterned using the first, second, or third film as a mask.