Block Copolymer Hot-Melt Adhesive for Processability and Bonding

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Solution Overview

Problem

Existing hot-melt adhesives do not provide sufficient improvements in adhesive properties, necessitating a composition that enhances processability and adhesive performance.

Innovation Solution

A block copolymer composition with specific molecular weights and alkyl radical scavengers, along with optional additives like tackifying resin and cross-linking agents, to create a hot-melt adhesive with improved processability and adhesive properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional hot-melt adhesives are used, then basic adhesive function is provided, but adhesive properties are insufficient and processability is poor

Engineering Contradiction:
Improveadhesive propertiesVSAvoidprocessability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by precisely controlling the weight average molecular weight (Mw) of the block copolymer within 300,000 to 800,000 and the alkyl radical scavenger content at 0.05 to 2 parts by mass per 100 parts of block copolymer. These parameter optimizations simultaneously improve adhesive properties and processability, resolving the technical contradiction between reliability and ease of manufacture.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite adhesive system by combining block copolymer A1 or A2 with specific alkyl radical scavengers (such as hindered phenol-based antioxidants). This composite formulation enhances both adhesive performance and processability through synergistic effects between the polymer matrix and functional additives.

Inventive Principle:
Principle #40Composite materials

2Strength

If block copolymer with high molecular weight is used, then adhesive strength is improved, but processability deteriorates

Engineering Contradiction:
Improveadhesive strengthVSAvoidprocessability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent resolves this contradiction by optimizing the weight average molecular weight parameter to a specific range of 300,000 to 800,000. This parameter change ensures sufficient adhesive strength while maintaining adequate processability, as molecular weights outside this range would either compromise strength (if too low) or hinder processing (if too high).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies partial action by using a moderate amount of alkyl radical scavenger (0.05 to 2 parts by mass) rather than excessive amounts. This controlled addition provides sufficient adhesive enhancement and processability improvement without causing adverse effects from over-addition, balancing strength and processability.

Inventive Principle:
Principle #16Partial or excessive action

3Reliability

If alkyl radical scavenger content is increased, then adhesive properties are improved, but manufacturing cost and complexity increase

Engineering Contradiction:
Improveadhesive propertiesVSAvoidcomposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies partial action by using a controlled amount of alkyl radical scavenger (0.05 to 2 parts by mass per 100 parts block copolymer). This moderate addition level provides sufficient adhesive property improvement while avoiding the complexity and cost associated with higher concentrations, thus resolving the contradiction between reliability and composition complexity.

Inventive Principle:
Principle #16Partial or excessive action

Solution Approach 2:

The patent optimizes the concentration parameter of the alkyl radical scavenger within a specific range (0.05 to 2 parts by mass). This parameter optimization achieves the desired adhesive properties while minimizing composition complexity, as both lower and higher concentrations would be suboptimal.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive composition exhibits excellent processability, thermal stability, and high adhesiveness, providing enhanced adhesive performance.

Implementation Method 1

The adhesive composition exhibits excellent processability, thermal stability, and high adhesiveness

Methodology Applied
Scientific EffectThermal stability:

Implementation Method 2

hot-melt adhesives are adhesives which can efficiently bond a variety of products because when cooled from a heat melted state, these solidify in a short time

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

when cooled from a heat melted state, these solidify in a short time

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 4

when cooled from a heat melted state, these solidify in a short time

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS20250333629A1Adhesive agent composition, hot-melt adhesive agent composition, and adhesive agent
Publication Date: 2025.10.30 ZEON CORP
  • US20250333629A1 patent drawing
  • US20250333629A1 patent drawing
  • US20250333629A1 patent drawing

AI summary

Provided is an adhesive composition comprising a block copolymer composition and an alkyl radical scavenger, the block copolymer composition containing a specific block copolymer A1 represented by General Formula (1) or a specific block copolymer A2 represented by General Formula (2), wherein the entire block copolymer composition has a weight average molecular weight (Mw) of 300,000 to 800,000, and the content of the alkyl radical scavenger is 0.05 to 2 parts by mass relative to 100 parts by mass of the content of the block copolymer composition.