Blown Film Polypropylene Composition Stiffness Transparency

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Solution Overview

Problem

The extrusion blown film process using polypropylene faces challenges in achieving good transparency and processing stability due to high haze levels and mechanical property limitations, particularly in achieving a balance between stiffness, toughness, and transparency.

Innovation Solution

A polypropylene composition comprising a random propylene copolymer, high melt strength polypropylene, and a viscous polypropylene, with specific branching indices and melt flow rates, along with an α-nucleating agent, to create a film with improved melt strength, strain hardening, and reduced haze.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high melt strength polypropylene is used to improve bubble stability during extrusion blown film process, then processing behavior is improved, but haze level increases and transparency deteriorates

Engineering Contradiction:
Improvebubble stabilityVSAvoidhaze level
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses a composite polypropylene composition consisting of three distinct polypropylene components with different properties: a first polypropylene (60-90 wt%) providing base film properties, a second polypropylene (5-30 wt%) with high melt strength (low MFR ≤ 5 g/10min) for bubble stability, and a third polypropylene (1-20 wt%) with very high melt flow (MFR ≥ 400 g/10min) to reduce haze. This composite approach allows simultaneous achievement of processing stability and transparency by balancing competing requirements through material composition.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically adjusts multiple parameters of the polypropylene components including melt flow rate (MFR), molecular weight distribution, comonomer content, and their relative proportions in the composition. By optimizing these parameters, the patent achieves a balance where the high melt strength component provides sufficient bubble stability while the high melt flow component minimizes haze, resolving the contradiction between processing behavior and transparency.

Inventive Principle:
Principle #35Parameter changes

2Strength

If polypropylene is used to replace polyethylene in extrusion blown films, then mechanical properties like stiffness are improved, but transparency and processing behavior remain problematic

Engineering Contradiction:
ImprovestiffnessVSAvoidtransparency
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent creates a composite polypropylene system that maintains the inherent stiffness advantage of polypropylene while adding transparency through the inclusion of high melt flow polypropylene component. The multi-component composition allows the film to exhibit both the mechanical rigidity of polypropylene and improved optical clarity, enabling polypropylene to effectively replace polyethylene in applications requiring both stiffness and transparency.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies different polypropylene components with specialized properties to different functional requirements: the first polypropylene provides base mechanical properties including stiffness, the second polypropylene with high melt strength specifically addresses processing stability and bubble formation, and the third polypropylene with very high melt flow specifically targets haze reduction and transparency improvement. This localized functional assignment resolves the contradiction between stiffness and transparency.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If conventional polypropylene composition is used for extrusion blown film, then production cost is reduced, but mechanical properties and transparency are insufficient

Engineering Contradiction:
Improveproduction costVSAvoidmechanical properties
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent develops a composite polypropylene composition that builds upon conventional single-component or simple blend formulations. By systematically combining three polypropylene components with specific property ranges and optimized proportions, the patent achieves superior mechanical properties and transparency while maintaining compatibility with existing extrusion blown film production processes, thus improving manufacturing precision without excessively increasing production cost.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs a dynamic multi-component system where each polypropylene component contributes differently under processing conditions. The varying melt flow rates and molecular characteristics of the three components create a synergistic effect during extrusion and blowing processes, enabling the film to achieve optimal mechanical properties and transparency that cannot be obtained with static conventional compositions.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in extrusion blown films with exceptional low haze values, good stiffness, and enhanced processing parameters, achieving a superior combination of mechanical properties and transparency.

Implementation Method 1

the clarifier (C) comprises at least one α-nucleating agent (N)

Methodology Applied
Scientific EffectNucleation: Nucleation

Implementation Method 2

the high melt strength polypropylene (HMS-PP) has a branching index g′ of less than 1.0, preferably a branching index g′ of 0.9 or less

Methodology Applied
Scientific EffectBranching:

Implementation Method 3

Tc is the crystallization temperature [° C.] of the extrusion melt blown film or of the polypropylene composition measured by DSC

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS8889753B2Blownfilm grade showing superior stiffness, transparency and processing behaviour
Publication Date: 2014.11.18 BOREALIS AG
  • US8889753B2 patent drawing
  • US8889753B2 patent drawing

AI summary

Extrusion blown film comprising a polypropylene composition, said polypropylene composition comprises a random propylene copolymer, a high melt strength polypropylene, a polypropylene and optionally a clarifier, wherein • the random propylene copolymer comprises units derived from propylene and at least another C2 to C20 α-olefin, • the high melt strength polypropylene has a branching index g′ of less than 1.0, the polypropylene (B) has a MFR2 (230° C.) of at least 400 g/10 min, • the clarifier comprises at least one α-nucleating agent, and wherein further • the branching index g′ of the random propylene copolymer and the branching index g′ of the polypropylene are higher than the branching index g′ of the high melt strength polypropylene, • the random propylene copolymer has lower melt flow rate MFR2 (230° C.) than the polypropylene, • the extrusion melt blown film and/or the polypropylene composition (i) fulfill(s) the equation (I) Tm−Tc<30 (I) wherein Tm is the melting tempareture [° C.] making up more than 50% of the total melting enthalpy Hm of the extrusion melt blown film or of the polypropylene composition; Tc is the crystallization temperature [° C.] of the extrusion melt blown film or of the polypropylene composition; and/or (ii) has (have) a melt flow rate MFR2 (230° C.) of 1.0 to 5.5 g/10 min.