Blue OLED Emission Layer Materials for Efficiency and Stability

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Solution Overview

Problem

There is a demand for light emitting diodes (LEDs) with high efficiency and stable performance in display devices, particularly in organic electroluminescence display devices, where materials capable of enhancing luminous efficiency are required.

Innovation Solution

A light emitting diode comprising a first and second electrode with a functional layer containing a condensed polycyclic compound represented by specific formulas, which includes an emission layer that can emit blue light and thermally activated delayed fluorescence, and is made of materials such as Ag, Mg, Cu, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, Li, Ca, LiF, Mo, Ti, W, In, Sn, and Zn, or mixtures thereof.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional emission layer materials are used in organic electroluminescence display devices, then the device structure can be maintained, but the luminous efficiency and stability are insufficient

Engineering Contradiction:
Improveluminous efficiencyVSAvoidstability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the emission layer material by introducing specific condensed polycyclic compounds with defined molecular formulas (Formula 1 and Formula 2). These structural parameter changes result in improved luminous efficiency and stability without altering the overall device structure, directly resolving the technical contradiction between efficiency and stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategy by combining the condensed polycyclic compound (Formula 1) with another compound (Formula 2) in the emission layer. This composite approach enhances both luminous efficiency and stability synergistically, overcoming the limitations of single-material systems while maintaining device structural integrity.

Inventive Principle:
Principle #40Composite materials

2Productivity

If new condensed polycyclic compounds are introduced to improve efficiency, then luminous performance is enhanced, but material complexity increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidmaterial complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent systematically varies specific parameters in the molecular structure (substituents R1-R6, ring positions a-d) of the condensed polycyclic compound to optimize performance. This parameter-based approach allows for efficient material design and selection without exponentially increasing complexity, as each parameter change can be independently optimized.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces functional groups at specific local positions (R1-R6 substituents at different ring positions) to achieve desired properties. This local modification strategy allows for targeted optimization of luminous efficiency without requiring complete redesign of the entire molecular structure, thereby controlling material complexity.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed polycyclic compound enhances the efficiency and stability of the LEDs, enabling high luminous efficiency and improved performance in display devices.

Implementation Method 1

holes and electrons injected from a first electrode and a second electrode, respectively, recombine in an emission layer, and thus a luminescent material in the emission layer emits light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

the emission layer may emit thermally activated delayed fluorescence

Methodology Applied
Scientific EffectThermally activated delayed fluorescence: Phosphorescence

Data Source

PatentUS12378469B2Light emitting diode and condensed polycyclic compound for the same
Publication Date: 2025.08.05 SAMSUNG DISPLAY CO LTD
  • US12378469B2 patent drawing
  • US12378469B2 patent drawing
  • US12378469B2 patent drawing

AI summary

A light emitting diode includes a first electrode, a second electrode, and at least one functional layer disposed between the first electrode and containing a condensed polycyclic compound represented by Formula 1. The first electrode and the second electrode each independently contain at least one selected from Ag, Mg, Cu, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, Li, Ca, LiF, Mo, Ti, W, In, Sn, and Zn, compounds selected thereof, and mixtures thereof. The light emitting diode may achieve improved luminous efficiency: