Blue OLED Organic Compound for Color Purity and Low Evaporation

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Solution Overview

Problem

Current organic light-emitting devices face challenges in achieving high color purity and long lifespan with low evaporation temperatures, which affects their reliability and efficiency.

Innovation Solution

Development of a novel organic compound represented by General Formula (G1) with specific structural features, such as branched alkyl groups and heteroaromatic ring skeletons, that enhance sublimation properties, solubility, and heat resistance, allowing for efficient blue light emission and reduced evaporation temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional organic compounds are used in light-emitting devices, then device structure can be maintained, but color purity is insufficient and evaporation temperature remains high

Engineering Contradiction:
Improvecolor purityVSAvoidevaporation temperature
Core Design Contradiction:
Illumination intensityVSTemperature

Solution Approach 1:

The patent modifies molecular parameters by introducing specific substituents (branched alkyl groups at positions 2 and 7 of the dibenzofuran ring, and tert-butyl groups on naphthyl rings) to change the physical and chemical properties of the organic compound, achieving both high color purity and reduced evaporation temperature

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite molecular structure combining dibenzofuran core with naphthyl groups and alkyl substituents, where each component contributes specific properties: dibenzofuran provides structural stability, naphthyl groups enhance color purity, and alkyl groups reduce evaporation temperature through steric effects

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If organic compounds with high color purity are developed, then light emission quality improves, but thermophysical properties and lifespan may be compromised

Engineering Contradiction:
Improvecolor purityVSAvoiddevice lifespan
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent applies different functional groups at specific positions of the molecular structure: dibenzofuran core for structural integrity and lifespan, naphthyl groups for color purity, and alkyl substituents for thermophysical property optimization, achieving local optimization of different properties within the same molecule

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If evaporation temperature is reduced for easier fabrication, then manufacturing process is simplified, but color purity and device performance may deteriorate

Engineering Contradiction:
Improvefabrication easeVSAvoidcolor purity
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The patent carefully balances molecular parameters by selecting specific alkyl group types and positions that reduce evaporation temperature through steric hindrance effects without significantly altering the electronic structure responsible for color emission, thus maintaining color purity while improving manufacturability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic compound enables the production of light-emitting devices with improved thermophysical properties, high color purity, and extended lifespan, facilitating easier fabrication and reliable performance.

Implementation Method 1

enhance sublimation properties, solubility, and heat resistance, allowing for efficient blue light emission and reduced evaporation temperatures

Methodology Applied
Scientific EffectSublimation: Sublimation

Implementation Method 2

Carriers are injected by application of voltage to the device, and recombination energy of the carriers is used, whereby light emission can be obtained from the light-emitting material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11925109B2Organic compound, light-emitting device, optical device, light-emitting apparatus, electronic device, and lighting device
Publication Date: 2024.03.05 SEMICON ENERGY LAB CO LTD
  • US11925109B2 patent drawing
  • US11925109B2 patent drawing
  • US11925109B2 patent drawing

AI summary

A novel organic compound with favorable thermophysical properties is provided. An organic compound represented by General Formula (G1) is provided. At least one of X1 to X5 is a secondary or tertiary alkyl group having 3 to 6 carbon atoms in which a carbon atom bonded to a phenyl group branches. Each of R1 to R7 is independently any of hydrogen, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, and an unsubstituted or alkyl-substituted aryl group having 6 to 13 carbon atoms. Ar1 represents a substituted or unsubstituted condensed heteroaromatic ring skeleton having 8 to 60 carbon atoms and composed of two or more aromatic rings, and Ar2 represents a substituted or unsubstituted aryl group having 6 to 25 carbon atoms. Furthermore, n is any of 1 to 3.