Cryogenic Boil-Off Gas Sorbent Storage for Hydrogen Tanks

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Solution Overview

Problem

The challenge of hydrogen boil-off in cryogenic storage tanks leads to fuel loss, inefficiency, and safety concerns, particularly in mobile applications due to thermal loading and pressure management issues.

Innovation Solution

A storage system comprising a primary tank for low latent heat of vaporization liquids and a secondary tank with a porous sorbent that reversibly stores boil-off gas, utilizing metal-organic frameworks or similar materials to capture and convert the boil-off gas for energy generation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If venting or pressure relief valves are used to manage boil-off gas, then safety is improved, but energy loss increases and system efficiency decreases

Engineering Contradiction:
ImprovesafetyVSAvoidenergy loss
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent converts the harmful boil-off gas into a useful resource by capturing it in the secondary storage tank and utilizing it for energy generation through fuel cells or combustion engines, thereby transforming the energy loss into a beneficial energy source

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

Instead of discarding boil-off gas through venting, the system recovers it by capturing the gas in the secondary storage tank and recovering its energy content for power generation, eliminating the need for energy loss while maintaining safety

Inventive Principle:
Principle #34Discarding and recovering

2Loss of energy

If recirculation systems are implemented to capture boil-off gas, then energy efficiency is improved, but device complexity increases

Engineering Contradiction:
Improveenergy efficiencyVSAvoidsystem complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The storage system is segmented into a primary storage tank for liquid hydrogen and a secondary storage tank for boil-off gas capture, allowing independent operation and simplifying the overall system architecture while maintaining energy efficiency

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The secondary storage tank acts as an intermediary component between the primary storage tank and the energy utilization system, buffering the boil-off gas and enabling flexible energy recovery without adding complex control mechanisms to the primary system

Inventive Principle:
Principle #24Intermediary (Mediator)

3Device complexity

If boil-off gas is vented to atmosphere, then pressure management is simplified, but environmental harm increases and energy is lost

Engineering Contradiction:
Improvepressure managementVSAvoidenvironmental harm
Core Design Contradiction:
Device complexityVSObject-generated harmful factors

Solution Approach 1:

The system converts the environmentally harmful venting of hydrogen gas into a beneficial process by capturing the gas in the secondary storage tank and utilizing it for energy generation, thereby eliminating environmental harm while maintaining simple pressure management

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Efficiently captures and converts boil-off gas, reducing fuel loss and enhancing system efficiency while ensuring safe and flexible operation across various applications.

Implementation Method 1

a secondary storage tank comprising a porous sorbent for reversibly storing a boil-off gas released from the primary storage tank

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20250354659A1System and method for storing liquids having low latent heat of vaporization
Publication Date: 2025.11.20 NUOVO PIGNONE TECH SRL
  • US20250354659A1 patent drawing
  • US20250354659A1 patent drawing

AI summary

Disclosed herein is a storage system for storing low latent heat of vaporization gases comprises a primary storage tank for storing a liquid having a latent heat of vaporization of less than or equal to 1000 joules per gram, and a secondary storage tank comprising a porous sorbent for reversibly storing a boil-off gas released from the primary storage tank.