Bonded Wafer Oxygen Ion Layer Removal via Oxidizing and HF Treatment

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Solution Overview

Problem

The existing methods for producing bonded wafers face challenges in achieving uniform thickness and complete removal of oxygen ion implanted layers, particularly when these layers are partially mixed with Si or SiOx, leading to defects and poor thickness distribution.

Innovation Solution

A method involving the direct bonding of wafers with oxygen ion implantation, followed by repetitive treatment with oxidizing solutions like ozone water and HF to effectively remove the oxygen ion implanted layer, improving thickness distribution and reducing defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If oxygen ion implantation is used to form an oxygen ion implanted layer, then it is possible to create a buried oxide film, but the layer becomes partially mixed with Si or SiOx and cannot be completely removed by conventional HF solution

Engineering Contradiction:
Improvequality of buried oxide filmVSAvoidremovability of oxygen ion implanted layer
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical parameters of the removal solution by combining oxidizing solution (to convert Si/SiOx to SiO2) with HF solution (to dissolve SiO2). This parameter change enables complete removal of the oxygen ion implanted layer while maintaining its quality as a buried oxide film.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite removal system consisting of oxidizing solution and HF solution working in sequence. The oxidizing solution component converts the mixed Si/SiOx layer into removable SiO2, while the HF solution component dissolves the oxidized layer, creating an effective composite removal mechanism.

Inventive Principle:
Principle #40Composite materials

2Productivity

If grinding and polishing is used to thin the wafer, then the active layer can be formed, but the thickness uniformity of the SOI layer deteriorates

Engineering Contradiction:
Improveefficiency of wafer thinningVSAvoidthickness uniformity of SOI layer
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent performs oxygen ion implantation and heat treatment to create a distinct buried oxide film structure before the grinding and polishing steps. This preliminary action establishes a defined interface that guides the subsequent thinning process, helping to maintain better thickness uniformity in the active layer.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces purely mechanical grinding and polishing with a combined chemical-physical approach. The oxygen ion implantation and heat treatment create a chemically distinct buried oxide layer that facilitates more controlled and uniform mechanical removal during thinning, improving thickness uniformity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If SIMOX method is used to produce bonded wafer, then buried oxide film can be formed, but different crystal orientations cannot be produced through the insulating layer

Engineering Contradiction:
Improvequality of buried oxide filmVSAvoidcrystal orientation flexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent segments the wafer structure into distinct layers: the active layer with its original crystal orientation, the oxygen ion implanted layer forming the buried oxide, and the support substrate. This segmentation allows each layer to have different properties and orientations independently, enabling versatility in crystal orientation while maintaining buried oxide quality.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies local quality by allowing different regions of the bonded wafer to have different crystal orientations. The active layer can maintain its original orientation while the support substrate can have a different orientation, and the buried oxide layer acts as an interface that accommodates this local variation.

Inventive Principle:
Principle #3Local quality

4Productivity

If grinding-polishing method is used to produce bonded wafer, then active layer can be formed, but the thickness uniformity of the active layer is poor

Engineering Contradiction:
Improveefficiency of bonded wafer productionVSAvoidthickness uniformity of active layer
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent performs oxygen ion implantation and heat treatment to create a distinct buried oxide film structure before the grinding and polishing steps. This preliminary action establishes a defined interface that guides the subsequent thinning process, helping to maintain better thickness uniformity in the active layer.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces purely mechanical grinding and polishing with a combined chemical-physical approach. The oxygen ion implantation and heat treatment create a chemically distinct buried oxide layer that facilitates more controlled and uniform mechanical removal during thinning, improving thickness uniformity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the effective removal of oxygen ion implanted layers and improves the in-plane thickness uniformity of the SOI layer, reducing defects and enhancing the quality of the final product.

Implementation Method 1

a step of implanting oxygen ions into the wafer for active layer to form an oxygen ion implanted layer in the active layer

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 2

a step of oxidizing the bonded wafer to form an oxide film on the exposed surface of the oxygen ion implanted layer

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

a step of removing the oxide film

Methodology Applied
Scientific EffectChemical etching:

Data Source

PatentUS7927972B2Method for producing bonded wafer
Publication Date: 2011.04.19 SUMCO CORP
  • US7927972B2 patent drawing
  • US7927972B2 patent drawing
  • US7927972B2 patent drawing

AI summary

Even if an oxygen ion implanted layer in a wafer for active layer is not a completely continuous SiO2 layer but a layer mixed partially with Si or SiOx, it is removed by here is provided a method for producing a bonded wafer in which it is possible to remove an oxygen ion implanted layer effectively as it is by repetitive treatment with an oxidizing solution and HF solution at a step of removing the oxygen ion implanted layer in a bonded wafer.