Borate Complex Semiconducting Layers for Organic Electronics

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Solution Overview

Problem

There is a need to improve the performance of organic electronic devices using borate complexes, specifically to enhance their lifetime and driving voltage, while also allowing for a broader selection of applicable matrix materials.

Innovation Solution

The use of borate complexes comprising metals such as Ca and Sr with heterocyclic groups as semiconducting layers in organic electronic devices, which allows for fine-tuning of the electronic structure and improved thermal properties, enabling a broader selection of matrix materials compared to Mg and Ba analogues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If borate complexes with Mg or Ba are used in organic electronic devices, then device performance is achieved, but lifetime and driving voltage characteristics are insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoiddriving voltage efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the metal parameter from Mg or Ba to Ca or Sr in the borate complex structure. This parameter change results in improved thermal stability and electronic properties, leading to enhanced device lifetime and driving voltage characteristics while maintaining good electron transport performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite borate complexes combining specific metals (Ca or Sr) with heterocyclic ligand structures. This composite approach allows optimization of both thermal properties and electronic structure, resolving the contradiction between device lifetime and driving voltage efficiency

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If borate complexes are used in organic electronic devices, then electron transport function is achieved, but selection of applicable matrix materials is limited

Engineering Contradiction:
Improvematrix material selectionVSAvoidthermal properties
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent modifies the metal center parameter in the borate complex from traditional options to Ca or Sr, which exhibits superior thermal stability. This parameter change enables the complex to be compatible with a broader range of matrix materials while maintaining reliable thermal properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The Ca and Sr borate complexes developed in the patent possess universal applicability across different matrix materials. The heterocyclic ligand structure combined with Ca or Sr metal centers creates a versatile compound that can function effectively in various organic electronic device configurations with different matrix materials

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS11527729B2Electronic devices including semiconducting layers comprising at least one borate complex and methods for preparing the same
Publication Date: 2022.12.13 NOVALED GMBH
  • US11527729B2 patent drawing
  • US11527729B2 patent drawing
  • US11527729B2 patent drawing

AI summary

Electronic devices and methods for preparing electronic devices. Electronic devices may include a semiconducting layer, which may include at least one borate complex. Borate complex may include a metal, such as Ca or Sr, and at least one borate ligand. Borate ligands may include a heterocyclic group. Methods may include evaporating a borate complex.