Borate Photocuring Resin for High-Density i-Line Waveguides

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Solution Overview

Problem

Existing resin compositions for optical waveguides lack sufficient photosensitivity for effective photocuring using direct imaging methods, particularly at i-line wavelengths, leading to inefficiencies in forming high-density optical waveguides with narrow pitches and multilayer structures.

Innovation Solution

A resin composition for optical waveguides containing an epoxy resin and a photocuring agent with a borate having a boron anion, which enhances photosensitivity to i-line light, allowing efficient photocuring and formation of high-density optical waveguides.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a resin composition uses an epoxy resin with conventional photocuring agents, then heat resistance is improved, but photosensitivity at i-line wavelengths deteriorates

Engineering Contradiction:
Improveheat resistanceVSAvoidphotosensitivity at i-line
Core Design Contradiction:
TemperatureVSIllumination intensity

Solution Approach 1:

The patent changes the chemical composition parameters of the photocuring agent system by introducing a borate compound with specific structural features (Formula 1) that has high absorption coefficient at i-line wavelengths (365-407 nm). This parameter change enables the resin composition to maintain epoxy resin heat resistance while achieving sufficient photosensitivity for direct imaging photocuring.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite photocuring system combining a borate compound (Formula 1) with optional co-photocuring agents (Formulae 2-4) and epoxy resin. This composite material approach synergistically combines the thermal stability of epoxy resin with the enhanced i-line photosensitivity of the borate compound, resolving the contradiction between heat resistance and photosensitivity.

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If the resin composition requires high degree of photosensitivity for direct imaging method, then positioning accuracy is improved, but curing completeness deteriorates

Engineering Contradiction:
Improvepositioning accuracyVSAvoidcuring completeness
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent optimizes the molecular structure parameters of the borate compound (Formula 1) to achieve balanced photosensitivity - high enough for precise direct imaging pattern formation but not so high that it causes premature or incomplete curing. The specific structural parameters (R1-R6 groups) are designed to provide appropriate light absorption characteristics.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a dynamic curing system where the borate compound enables progressive curing - initial rapid curing for pattern definition followed by continued curing to achieve complete crosslinking. This dynamic behavior allows both high positioning accuracy during exposure and complete curing afterward.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables high-degree photocurability, resulting in optical waveguides with reduced optical loss and improved heat resistance, suitable for high-density wiring applications.

Implementation Method 1

a process step of photocuring a resin composition for optical waveguides by irradiating the resin composition with a light ray

Methodology Applied
Scientific EffectPhotocuring: Photopolymerisation

Implementation Method 2

The DI method has attracted a lot of attention from the art because the DI method allows an exposure pattern to be formed with high positioning accuracy even without using a photomask when irradiating the target with a light ray. A light source for use in the DI method has, in most cases, a wavelength of 365 nm or 407 nm, at which the resin composition for optical waveguides to be photocured needs to have a high degree of photosensitivity

Methodology Applied
Scientific EffectPhotosensitivity enhancement: Photoelectric Effect

Data Source

PatentUS20250215148A1Resin composition for optical waveguides, dry film for optical waveguides, and optical waveguide
Publication Date: 2025.07.03 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US20250215148A1 patent drawing
  • US20250215148A1 patent drawing
  • US20250215148A1 patent drawing

AI summary

A resin composition according to the present disclosure is designed for use in optical waveguides. The resin composition contains an epoxy resin (A) and a photocuring agent (B). The photocuring agent (B) includes a borate (B-1) having a boron anion.