Boric Acid Slurry for Subterranean Crosslinker Delivery

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Solution Overview

Problem

Current methods for delivering crosslinkers to subterranean formations require large volumes and high costs due to limited solubility and logistical challenges, and existing viscosifiers often require bulk transportation and are not stable under formation conditions.

Innovation Solution

Aqueous crosslinker slurry compositions containing boric acid and a pH adjusting agent are used to create a treatment fluid with a boron concentration of 1.7% or greater by weight, combined with a viscosifier and aqueous medium, allowing for a more concentrated and stable delivery system that reduces transportation needs and enhances crosslinking properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional crosslinker delivery methods are used, then crosslinking function is achieved, but large volumes and high transportation costs are required due to limited solubility

Engineering Contradiction:
Improvevolume of crosslinker solutionVSAvoidtransportation and delivery complexity
Core Design Contradiction:
Quantity of substanceVSEase of manufacture

Solution Approach 1:

The patent changes the concentration parameter of the crosslinker solution from conventional low concentrations to a highly concentrated aqueous slurry with boron at 1.7% or greater by weight. This parameter change reduces the volume of solution required for effective crosslinking, thereby reducing transportation costs and logistical complexity while maintaining the crosslinking function.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If existing viscosifiers are used, then viscosity is achieved, but bulk transportation is required and stability under formation conditions is insufficient

Engineering Contradiction:
Improvestability under formation conditionsVSAvoidbulk transportation requirement
Core Design Contradiction:
Stability of the object's compositionVSWeight of moving object

Solution Approach 1:

The patent modifies the concentration and composition parameters of the aqueous crosslinker slurry, achieving a highly concentrated formulation (1.7% or greater boron by weight) that is stable under subterranean formation conditions. This eliminates the need for bulk transportation of dilute solutions and ensures compositional stability during transport and application.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a cost-effective, stable, and efficient method for treating subterranean formations by minimizing the volume of solution required, maintaining viscosity under varying temperature and pressure conditions, and allowing for lower material usage at the wellsite, thereby optimizing fracturing fluid performance.

Implementation Method 1

The crosslinkers are selected for their ability to encourage crosslinking of the viscosifier depending upon the formation conditions and viscosifier properties

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

combining the composition with a mixture comprising a viscosifier and aqueous medium to form a treatment fluid

Methodology Applied
Scientific EffectPolymer crosslinking: Chemical Bonding

Data Source

PatentUS9284483B2Aqueous crosslinker slurry compositions and applications
Publication Date: 2016.03.15 SCHLUMBERGER TECH CORP
  • US9284483B2 patent drawing
  • US9284483B2 patent drawing
  • US9284483B2 patent drawing

AI summary

A method and composition for treating a subterranean formation penetrated by a wellbore including preparing an aqueous composition containing a source of boron, whereby boron is present in the slurry in an amount of about 1.7% or greater, by weight, based upon a total weight of the composition, combining the composition with a mixture comprising a viscosifier and aqueous medium to form a treatment fluid, wherein the composition is added to the mixture in an amount of about 0.5% or less, by volume, based upon a total volume of the treatment fluid, and contacting the formation with the treatment fluid to treat the formation. The source of boron may be boric acid.