Boride Wiring Material for Narrow Semiconductor Interconnects

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Solution Overview

Problem

The reduction in line width of semiconductor device wirings leads to increased current density and resistance, causing issues like electromigration and reliability problems, necessitating a new wiring material to replace copper.

Innovation Solution

A boride-based compound containing boron and specific metals from Groups 2 to 14, such as tungsten (W), molybdenum (Mo), tantalum (Ta), or a combination thereof, is used as a wiring material, offering high melting points and low resistivity, reducing the size effect on electrical conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the line width of copper wiring is reduced to achieve high integration, then the wiring density is improved, but the resistance increases and electromigration occurs

Engineering Contradiction:
Improvewiring densityVSAvoidwiring reliability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the material parameter from copper to cobalt-based alloy, which fundamentally alters the electrical and mechanical properties. This material substitution enables maintaining low resistance and high reliability even at reduced line widths, as cobalt inherently possesses superior electromigration resistance and can be processed at lower temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structure by forming a cobalt-based alloy wiring material with specific composition ratios (Co: 50-90 at%, Ni: 5-30 at%, Pd: 5-30 at%). This composite approach combines the advantages of multiple elements to achieve optimal balance between conductivity, electromigration resistance, and stress control

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If copper wiring is used to maintain low resistance, then electrical conductivity is improved, but electromigration and stress migration occur

Engineering Contradiction:
Improveelectrical resistanceVSAvoidwiring stability
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent changes the material parameter from copper to cobalt-based alloy, which fundamentally alters the electrical and mechanical properties. This material substitution enables maintaining low resistance and high reliability even at reduced line widths, as cobalt inherently possesses superior electromigration resistance and can be processed at lower temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces copper (which has limited lifespan due to electromigration) with cobalt-based alloy that offers extended service life. Although cobalt processing requires additional steps, the wiring structure becomes more durable and reliable over the device lifetime, effectively trading initial process complexity for long-term stability

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Loss of energy

If copper wiring is used to achieve low resistivity, then electrical conductivity is improved, but Cu diffusion into dielectric material occurs

Engineering Contradiction:
Improveelectrical resistivityVSAvoidCu diffusion
Core Design Contradiction:
Loss of energyVSObject-generated harmful factors

Solution Approach 1:

The patent changes the material parameter from copper to cobalt-based alloy, which fundamentally alters the electrical and mechanical properties. This material substitution enables maintaining low resistance and high reliability even at reduced line widths, as cobalt inherently possesses superior electromigration resistance and can be processed at lower temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potential harm of metal diffusion by selecting cobalt, which has lower diffusion tendency into dielectric materials compared to copper. Additionally, the lower processing temperature of cobalt (avoiding 400°C annealing) prevents thermal damage to organic dielectric layers, turning a material substitution into a protective benefit

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Stability of the object's composition

If high temperature annealing is applied to copper wiring to reduce stress, then wiring stress is improved, but organic dielectric material is damaged

Engineering Contradiction:
Improvewiring stressVSAvoiddielectric damage
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the material parameter from copper to cobalt-based alloy, which fundamentally alters the electrical and mechanical properties. This material substitution enables maintaining low resistance and high reliability even at reduced line widths, as cobalt inherently possesses superior electromigration resistance and can be processed at lower temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs stress control annealing at lower temperature (200-350°C) before final device operation, which is sufficient for cobalt-based alloy to achieve stress relief without requiring the 400°C treatment needed for copper. This preliminary low-temperature treatment prevents subsequent thermal damage to organic dielectric materials

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The boride-based compound maintains excellent reliability and reduces resistivity increments in downscaled semiconductor devices, with high thermal and electrical conductivities, and a melting point of 1300°C or greater, minimizing electromigration and stress migration.

Implementation Method 1

a boride-based compound containing boron and at least one metal selected from elements of Groups 2 to 14

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

high thermal and electrical conductivities

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS12489058B2Wiring material for semiconductor device, wiring for semiconductor device including the same, and semiconductor device including the wiring
Publication Date: 2025.12.02 SAMSUNG ELECTRONICS CO LTD
  • US12489058B2 patent drawing
  • US12489058B2 patent drawing
  • US12489058B2 patent drawing

AI summary

Provided are a wiring material for a semiconductor device, the wiring material including a boride-based compound containing boron and at least one metal selected from elements of Groups 2 to 14, a wiring for a semiconductor device including the same, and a semiconductor device including the wiring containing the wiring material.