Joint-Free Boron Cask Liner via Hot Isostatic Pressing

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Solution Overview

Problem

Conventional methods for manufacturing Al-B4C metal matrix composite (MMC) sheets for nuclear fuel storage casks face challenges such as limited boron concentration, non-homogeneous distribution of B4C ceramic, and complex processing steps like casting and extrusion, which result in inconsistent neutron absorption and potential neutron flux leakage at joints.

Innovation Solution

The use of near-net shape (NNS) hot isostatic pressing (HIP) to form a boron-containing composition directly into a hollow cylindrical cask liner with a uniform B4C distribution, eliminating the need for extrusion and rolling, and incorporating mechanical alloying to optimize B4C distribution within the aluminum matrix, thereby creating a single, joint-free liner with enhanced neutron absorption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional casting or powder blending methods are used to manufacture Al-B4C MMC sheets, then the manufacturing process can be completed, but the B4C ceramic distribution becomes non-homogeneous and the boron concentration is limited

Engineering Contradiction:
ImproveB4C ceramic distribution uniformityVSAvoidboron concentration
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The patent changes the manufacturing parameters by using hot isostatic pressing (HIP) instead of conventional casting or powder blending. This process applies high pressure and temperature to densify the composite material, achieving homogeneous B4C distribution and enabling higher boron concentrations (up to 20-25 wt% B4C) that were not achievable with traditional methods.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining aluminum matrix with B4C ceramic particles, where the composite structure allows for optimized distribution of the ceramic phase throughout the metal matrix, achieving both homogeneity and high boron content through the HIP process.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional casting and extrusion processes are used, then Al-B4C MMC sheets can be produced, but the processing steps become complex and neutron absorption consistency deteriorates

Engineering Contradiction:
Improveprocessing complexityVSAvoidneutron absorption consistency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent extracts and eliminates the complex extrusion and rolling steps from the conventional manufacturing process. By using hot isostatic pressing directly to form the desired shapes, the process simplifies production while ensuring homogeneous B4C distribution throughout the material, thereby maintaining consistent neutron absorption properties.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the processing parameters by replacing multi-step mechanical processing (casting, extrusion, rolling) with a single hot isostatic pressing step. This parameter change simplifies the manufacturing process and ensures uniform material properties for consistent neutron absorption.

Inventive Principle:
Principle #35Parameter changes

3Strength

If boron containing stainless steel is used for cask liner, then the material has sufficient strength, but the boron concentration is limited to 2% and the material becomes brittle

Engineering Contradiction:
Improvematerial strengthVSAvoidboron concentration
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The patent uses an aluminum-based composite material (Al-B4C MMC) instead of boron-containing stainless steel. This composite approach allows incorporating high concentrations of B4C ceramic particles (20-25 wt%) into the aluminum matrix, achieving both high boron content for neutron absorption and sufficient mechanical strength without the brittleness issues of boron steel.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the base material from steel to aluminum, fundamentally altering the material system. This parameter change enables much higher boron concentrations to be incorporated while maintaining ductility and formability, as aluminum can accommodate high volumes of ceramic particles without becoming brittle like steel.

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If Al-B4C MMC sheets are joined by welding or mechanical techniques, then the cask liner can be assembled, but neutron flux leakage may occur at the joints

Engineering Contradiction:
Improveassembly capabilityVSAvoidneutron flux leakage prevention
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent merges the manufacturing steps to create large monolithic components using hot isostatic pressing, eliminating the need for joining multiple sheets together. This consolidation removes the joints that could potentially leak neutrons, while still enabling manufacturing of large-scale cask liners through direct forming of the composite material.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a more efficient, cost-effective, and reliable neutron-absorbing cask liner with improved homogeneity and reduced risk of neutron flux leakage, allowing for higher boron content and simplified manufacturing without the need for complex processing steps, thus enhancing the safety and efficiency of nuclear fuel storage.

Implementation Method 1

The 10B isotope is a strong neutron absorber, leading to the usefulness of boron as a cask liner material

Methodology Applied
Scientific EffectNeutron absorption: Absorption (physical)

Implementation Method 2

The use of near-net shape (NNS) hot isostatic pressing (HIP) to form a boron-containing composition directly into a hollow cylindrical cask liner

Methodology Applied
Scientific EffectHot isostatic pressing: Hot Isostatic Pressing

Implementation Method 3

incorporating mechanical alloying to optimize B4C distribution within the aluminum matrix

Methodology Applied
Scientific EffectMechanical alloying:

Implementation Method 4

aluminum has higher thermal conductivity compared to steel which can be advantageous for heat management within the storage casks

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS11951545B2Moderated nuclear cask composite
Publication Date: 2024.04.09 MATERION CORP
  • US11951545B2 patent drawing
  • US11951545B2 patent drawing
  • US11951545B2 patent drawing

AI summary

A cask liner includes a hollow cylinder comprising a boron-containing composition. The hollow cylinder has no longitudinal joints. The hollow cylinder may be formed as a single unit by isostatic pressing, for example by hot isostatic pressing (HIP) of a blend of a boron-containing powder and an aluminum or aluminum alloy powder which is blended by mechanical alloying. Casked nuclear fuel includes a nuclear fuel rod comprising uranium, which is disposed in or extends through the hollow cylinder of the cask liner.