Boron Doped Diamond Conductivity Sensor for High Temperature Steam

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Solution Overview

Problem

Current methods for measuring conductivity in steam generating systems require cooling the water, which is inefficient and disrupts system operation, and there is a need for real-time monitoring to detect issues like mineral scale and corrosion.

Innovation Solution

A boron doped diamond based electrochemical band sensor is used to measure conductivity in-situ at high temperatures, allowing for real-time monitoring without cooling the system, using a diamond body with boron doped diamond band electrodes that can operate from 250° F to 1200° F.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional conductivity probes are used to measure water quality, then measurement accuracy is maintained, but the system must be cooled down to 100° F. or below, which interrupts operation and reduces productivity

Engineering Contradiction:
Improveconductivity measurement accuracyVSAvoidsystem operation continuity
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent changes the material parameter of the electrode from conventional materials to boron-doped diamond, which fundamentally alters the temperature resistance parameter. This allows the measurement system to operate at high temperatures (250-1200° F.) without cooling, maintaining measurement precision while enabling continuous operation and eliminating productivity loss from system shutdowns.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the steam generating system is cooled down for measurement, then probe protection is achieved, but real-time monitoring capability is lost

Engineering Contradiction:
Improveprobe protectionVSAvoidreal-time monitoring capability
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The boron-doped diamond material changes the thermal resistance parameter of the electrode, enabling it to withstand high temperatures without cooling. This allows the probe to remain protected and functional simultaneously, providing real-time monitoring capability while operating in the high-temperature steam environment.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent enables continuous measurement action by eliminating the cooling step. The boron-doped diamond electrode maintains its functionality continuously at high temperatures, allowing uninterrupted real-time monitoring of conductivity parameters in the steam generating system.

Inventive Principle:
Principle #20Continuity of useful action

3Productivity

If conventional electrodes are used at high temperature, then system operation can continue, but the electrode material degrades and measurement reliability decreases

Engineering Contradiction:
Improvecontinuous operation capabilityVSAvoidmeasurement reliability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent uses boron-doped diamond, which is a composite material combining the structural stability of diamond with the electrical conductivity properties introduced by boron doping. This composite material maintains both mechanical integrity and electrical functionality at high temperatures, ensuring measurement reliability while enabling continuous operation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The boron doping parameter fundamentally changes the material properties of the electrode, transforming it from a temperature-sensitive conventional material to a high-temperature-resistant material. This parameter change allows the electrode to maintain measurement reliability continuously at elevated temperatures without degradation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables continuous, real-time conductivity monitoring without interrupting steam generating system operations, reducing maintenance costs and improving safety by allowing for immediate detection of conductivity deviations and control of unwanted solids, and can be applied to various high-temperature steam systems including hydrothermal liquefaction units.

Implementation Method 1

The conductivity is measured by applying voltage to the boron doped diamond based electrochemical band sensor

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS9921177B2Method of measuring and monitoring conductivity in-situ in high temperature aqueous systems
Publication Date: 2018.03.20 BAKER HUGHES CO

AI summary

Monitoring of conductivity within a steam generating system may proceed in real time and without interruption of the steam generating system by use of a boron doped diamond based electrochemical band sensor placed within the steam generating system. The boron doped diamond based electrochemical band sensor has a diamond body and a plurality of boron doped diamond band electrodes disposed within the diamond body. At least a portion of each of the plurality of boron doped diamond band electrodes is doped with boron to provide metallic conduction.