Boron Extraction via Nanofiltration and Selective Resin

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Solution Overview

Problem

Boron accumulation in agricultural soils can lead to toxicity and crop failures due to its high solubility, causing fluctuations between deficiency and excess depending on rainfall and drought conditions, impacting crop yields.

Innovation Solution

A system utilizing a pressurized vessel with a boron-selective resin to extract boron from feed water, followed by acid-based and caustic solutions to regenerate the resin, and a nanofiltration system to process boron solutions for boric acid extraction, creating a closed-loop system with minimal waste.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If boron is left in the soil for agricultural use, then crop growth is stimulated, but boron accumulation leads to toxicity and crop failures

Engineering Contradiction:
Improvecrop growth stabilityVSAvoidboron toxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts boron from contaminated soil using chelating agents that form soluble complexes with boron, allowing it to be removed via irrigation water. This separation removes the harmful accumulated boron while preserving the soil structure and other nutrients.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system recovers boron from the extracted solution and returns it to the soil at controlled rates, preventing both toxicity and deficiency. This closed-loop approach discards the harmful concentrated form while recovering the beneficial element for controlled reapplication.

Inventive Principle:
Principle #34Discarding and recovering

2Object-affected harmful factors

If boron is removed from the soil to prevent toxicity, then boron accumulation is reduced, but boron deficiency occurs leading to reduced yields

Engineering Contradiction:
Improveboron accumulationVSAvoidcrop yield
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The system implements feedback control by monitoring soil boron levels and adjusting the rate of boron return accordingly. When soil boron levels are high, extraction continues; when levels are adequate, boron is returned to the soil at controlled rates to maintain optimal levels for crop growth.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent changes the chemical parameters of boron by converting it from insoluble soil-bound forms to soluble chelate complexes during extraction, and then controlling the reapplication rate to maintain optimal concentration levels in the soil.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If high rainfall occurs, then boron is leached from the soil causing deficiency, but drainage water contains lost boron that could be recovered

Engineering Contradiction:
Improvenatural boron distributionVSAvoidboron loss
Core Design Contradiction:
Ease of operationVSLoss of substance

Solution Approach 1:

The system converts the harmful effect of boron leaching during rainfall into a benefit by capturing the boron-rich drainage water and recovering the boron for reapplication to the soil. What was previously a loss mechanism becomes a recovery and redistribution opportunity.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Object-affected harmful factors

If conventional boron extraction methods are used, then boron can be removed from soil, but the processes are complex and disruptive to agricultural operations

Engineering Contradiction:
Improveboron removalVSAvoidextraction process complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The system uses naturally occurring chelating agents in the soil and irrigation water to perform the extraction, eliminating the need for complex external extraction equipment. The process leverages natural chemical reactions between chelators and boron, followed by simple water flushing to remove the boron-chelate complexes.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This system effectively manages boron levels in agricultural settings by extracting and recycling boron, reducing waste and operational disruptions, and providing a stable source of boron for fertilization, thus improving crop performance and yield stability.

Implementation Method 1

a nanofiltration system to process boron solutions for boric acid extraction

Methodology Applied
Scientific EffectNanofiltration: Semipermeable Membrane

Implementation Method 2

a pressurized vessel with a boron-selective resin to extract boron from feed water

Methodology Applied
Scientific EffectSelective adsorption: Adsorption

Data Source

PatentUS12151943B1System and method for extracting boric acid from a boron solution
Publication Date: 2024.11.26 PUMPHREY KIRK M
  • US12151943B1 patent drawing
  • US12151943B1 patent drawing
  • US12151943B1 patent drawing

AI summary

In a method for extracting boric acid from boron solution, the boron solution is processed at a nanofiltration system, wherein the nanofiltration system generates a first permeate and a first concentrate. The first permeate is stored in a first storage tank. The first permeate is polished to generate a second permeate and a second concentrate. The second concentrate is stored in a second storage tank. The second concentrate is processed at a seawater processing system to generate a third concentrate and a third permeate, wherein the third concentrate comprises boric acid. The third concentrate is stored in a third storage tank.