Boron Filled Trench Isolation Structures

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Solution Overview

Problem

Conventional trench isolation structures in semiconductor devices often form voids during the filling process, especially in high aspect ratio trenches, leading to improper filling and ineffective isolation due to the limitations of oxide filling materials.

Innovation Solution

Using boron as a trench filler material, deposited through an atomic layer deposition technique or chemical vapor deposition, which is more resistant and less prone to void formation, and forming a barrier or adhesion layer to prevent diffusion and enhance adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If oxide filling is used in high aspect ratio trenches, then the filling process becomes difficult, but void formation increases and isolation effectiveness decreases

Engineering Contradiction:
Improvefilling qualityVSAvoidisolation effectiveness
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the material parameter from oxide to boron, which has different physical and chemical properties including lower vapor pressure and better conformal deposition characteristics, enabling successful filling of high aspect ratio trenches without void formation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the chemical vapor deposition process with atomic layer deposition, which provides better control over the deposition process and enables complete filling of high aspect ratio trenches by depositing material in atomic layers

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If trench aspect ratio increases, then isolation capability improves, but void formation during filling increases

Engineering Contradiction:
Improveisolation capabilityVSAvoidfilling completeness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the filling material from oxide to boron, which can be deposited conformally in high aspect ratio trenches without forming voids, thus maintaining filling completeness while achieving the required isolation capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a barrier layer as an intermediary between the trench wall and the boron filling material, which prevents boron diffusion into the substrate and enables complete filling of high aspect ratio trenches

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The boron-filled apertures provide effective electrical isolation with reduced leakage currents and voids, enabling reliable filling of high aspect ratio trenches and improving the integrity of semiconductor device isolation structures.

Implementation Method 1

deposited through an atomic layer deposition technique

Methodology Applied
Scientific EffectAtomic layer deposition: Physical Vapour Deposition

Implementation Method 2

chemical vapor deposition

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 3

forming a barrier or adhesion layer to prevent diffusion and enhance adhesion

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS9093266B2Forming high aspect ratio isolation structures
Publication Date: 2015.07.28 MICRON TECHNOLOGY INC
  • US9093266B2 patent drawing
  • US9093266B2 patent drawing
  • US9093266B2 patent drawing

AI summary

An isolation structure, such as a trench isolation structure, may be formed by forming an aperture in a semiconductor substrate and then filling the aperture with boron. In some embodiments, the aperture filling may use atomic layer deposition. In some cases, the boron may be amorphous boron. The aperture may be a high aspect ratio aperture, such as a trench, in some embodiments.