Boron Micro-Structured Neutron Detector With Conformal Doping

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Solution Overview

Problem

Existing semiconductor neutron detectors face limitations in detection efficiency, particularly thin-film-coated planar detectors, which are limited to 5% efficiency compared to 70% for helium-based gas detectors, and scaling other materials for commercial applications is difficult due to availability, environmental hazards, and production techniques.

Innovation Solution

A thermal neutron detector using isotopically enriched boron in both the neutron conversion layer and as a source for conformal doping, with micro-structured diodes having cavities filled with boron-containing materials, enabling a continuous conductive layer through solid-state diffusion, enhancing detection efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If thin-film-coated planar detectors are used, then the device structure is simple, but the detection efficiency is limited to 5%

Engineering Contradiction:
Improvedevice structure simplicityVSAvoiddetection efficiency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The detector is segmented into micro-structured cavities etched in the semiconductor substrate, with each cavity filled with boron-containing material. This segmentation increases the total surface area for neutron conversion while maintaining a planar overall structure, resolving the contradiction between structural simplicity and detection efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from a two-dimensional planar surface to a three-dimensional micro-structured surface with cavities. This dimensional change increases the effective area for neutron interaction without significantly complicating the manufacturing process, as the cavities can be formed using standard semiconductor fabrication techniques.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Reliability

If other semiconductor materials are used, then detection efficiency may be improved, but availability, environmental hazards, and production techniques become problematic

Engineering Contradiction:
Improvedetection efficiencyVSAvoidmaterial availability and production
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention uses boron-containing materials that serve dual functions: as a neutron conversion layer and as a p-type dopant source for conformal doping of the semiconductor substrate. This multi-functionality eliminates the need for separate doping materials, simplifying manufacturing while maintaining high detection efficiency through enhanced carrier collection.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If conformal doping is performed using boron as dopant source, then carrier collection is improved, but additional fabrication steps are required

Engineering Contradiction:
Improvecarrier collectionVSAvoidfabrication steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention merges the neutron conversion function and the doping function into a single material (boron-containing material). The same material that converts neutrons also serves as the dopant source, combining two previously separate functions into one, thereby reducing overall device complexity despite adding conformal doping capability.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The boron-containing material in the cavities serves itself by providing boron atoms that diffuse into the semiconductor substrate during thermal processing, creating the conformal doping layer. This self-service mechanism eliminates the need for separate doping steps and materials, reducing fabrication complexity while improving carrier collection.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves high detection efficiency, up to 37% in simulations, by utilizing boron as both a neutron conversion layer and conformal doping source, significantly improving performance over conventional detectors.

Implementation Method 1

The most common reactions used to create a charged particle from neutron interaction is 10B(n,α)7Li and 6Li(n,α)3H reactions

Methodology Applied
Scientific EffectNuclear reaction (10B(n,α)7Li): Nuclear Fission

Implementation Method 2

As these charged reaction products travel through the detection media, they generate secondary reaction products by ionization, which will eventually contribute to an electrical signal

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 3

These generated charges are separated by the applied electric field and collected at the contacts

Methodology Applied
Scientific EffectElectric field: Electric Field

Implementation Method 4

The substrate with the filled cavities can then be thermally treated for the solid-state diffusion of boron into the semiconductor (e.g., silicon or germanium) substrate, giving a continuous, conformal conductive layer

Methodology Applied
Scientific EffectSolid-state diffusion: Diffusion

Data Source

PatentUS12546907B2Neutron detectors and methods of fabricating the same using boron as neutron conversion layer and conformal doping source
Publication Date: 2026.02.10 BOARD OF RGT THE UNIV OF TEXAS SYST
  • US12546907B2 patent drawing
  • US12546907B2 patent drawing
  • US12546907B2 patent drawing

AI summary

Thermal neutron detectors and methods of fabricating the same are provided. A thermal neutron detector can use boron in both the neutron conversion layer and as a source for conformal doping in a semiconductor substrate. The neutron detector can be a micro-structured diode with cavities having a depth of 60 microns or less. The boron can be filled in the cavities and diffused into the semiconductor substrate via a diffusion annealing process.