Boron Organic Compound for Light-Emitting Device Efficiency

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Solution Overview

Problem

Current light-emitting devices face challenges in achieving low driving voltage, improved luminescence efficiency, and extended lifespan, particularly due to reactions between boron-containing compounds and electron-donating materials.

Innovation Solution

An organic compound represented by Formula 1 is introduced, which includes a boron atom protected by a bulky structure to prevent reactions with electron-donating materials, ensuring the boron remains in a 3-coordinated planar state, thereby maintaining the light-emitting device's efficiency and longevity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If boron-containing compounds are used in light-emitting devices, then luminescence efficiency can be improved, but reactions with electron-donating materials occur causing device degradation

Engineering Contradiction:
Improveluminescence efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent introduces an electron-donating unit as an intermediary component that mediates between the boron atom and external electron-donating materials. This intermediary unit satisfies the electron deficiency of the boron atom through internal electron donation, preventing external materials from reacting with the boron center while maintaining the desired luminescence properties

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the electronic parameters of the boron-containing compound by introducing specific electron-donating units (such as amino groups or N-heterocyclic carbenes) directly attached to the boron center. This changes the electron density distribution and HOMO-LUMO energy levels, making the compound less reactive toward external electron-donating materials while preserving luminescence efficiency

Inventive Principle:
Principle #35Parameter changes

2Power

If conventional organic compounds are used, then device operation is maintained, but driving voltage remains high and luminescence efficiency is limited

Engineering Contradiction:
Improvedriving voltageVSAvoidluminescence efficiency
Core Design Contradiction:
PowerVSLoss of energy

Solution Approach 1:

The patent systematically changes the molecular parameters of the organic compound by incorporating boron atoms with specific coordination geometries and electron-donating units. This modifies the HOMO-LUMO energy gap and charge carrier mobility parameters, enabling lower driving voltages while simultaneously improving luminescence efficiency through enhanced electron-hole recombination at the boron center

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite molecular structures combining boron centers with organic ligands containing electron-donating units. This composite approach integrates the advantages of boron-based luminescence with the stability and tunability of organic materials, achieving both low driving voltage and high luminescence efficiency in a single material system

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the organic compound results in a light-emitting device with reduced driving voltage, enhanced luminescence efficiency, and improved lifespan by preventing unwanted reactions and maintaining the boron atom's structural integrity.

Implementation Method 1

The organic compound may include a boron atom and a bulky structure that prevents or inhibits a reaction between the boron atom and an electron-donating material, such as a Lewis base

Methodology Applied
Scientific EffectSteric protection:

Implementation Method 2

ensuring the boron remains in a 3-coordinated planar state, thereby maintaining the light-emitting device's efficiency and longevity

Methodology Applied
Scientific EffectCoordination geometry stabilization:

Implementation Method 3

Holes injected from the first electrode may move toward the emission layer through the hole transport region. Electrons injected from the second electrode may move toward the emission layer through the electron transport region. Carriers, such as the holes and electrons, recombine in the emission layer to produce excitons. As the excitons transition from an excited state to a ground state, light may be generated.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240341185A1Organic compound, light-emitting device including the same, and electronic apparatus including the light-emitting device
Publication Date: 2024.10.10 SAMSUNG DISPLAY CO LTD
  • US20240341185A1 patent drawing
  • US20240341185A1 patent drawing
  • US20240341185A1 patent drawing

AI summary

Embodiments provide an organic compound, a light-emitting device, an electronic apparatus that includes the light-emitting device, and an electronic equipment light-emitting device. The light-emitting device includes a first electrode, a second electrode facing the first electrode, an interlayer between the first electrode and the second electrode and including an emission layer, and the organic compound. The organic compound is represented by Formula 1, which is explained in the specification: