Boronic Heterocyclic Compounds for OLED Lifespan and Efficiency

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Solution Overview

Problem

Existing organic electroluminescence devices face challenges in improving lifespan, color purity, efficiency, and operating voltage, particularly for emitters and matrix materials used in phosphorescent or fluorescent devices.

Innovation Solution

Development of boron and nitrogen-containing heterocyclic compounds with specific structural formulas, which serve as emitters or matrix materials in organic electroluminescence devices, enhancing their performance by improving solubility, processability, and device properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If conventional phosphorescent organometallic complexes or fluorescent compounds are used as emitting materials, then electroluminescence is achieved, but device lifetime and efficiency remain insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoiddevice performance consistency
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent modifies the molecular structure of emitting materials by introducing specific heterocyclic groups (triazole, tetrazole, pyrazole) and adjusting substituent patterns to optimize photophysical properties. This structural parameter change leads to improved quantum yields and enhanced device lifetime while maintaining stable performance across operating conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs composite material systems combining organic heterocyclic compounds with specific host materials and encapsulation layers. This multi-component approach creates synergistic effects that enhance device lifetime, improve efficiency, and ensure consistent performance while addressing the limitations of single-material systems

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If existing heterocyclic compounds are used as emitters, then electroluminescence is achieved, but color purity and efficiency are insufficient

Engineering Contradiction:
Improvecolor purityVSAvoidelectroluminescence efficiency
Core Design Contradiction:
Manufacturing precisionVSLoss of energy

Solution Approach 1:

The patent introduces specific functional groups (boronic acid esters, heterocyclic rings) at targeted positions within the molecular structure to locally enhance electron-hole recombination efficiency. This localized modification improves both color purity through controlled emission wavelengths and efficiency through enhanced radiative recombination at the specific molecular sites

Inventive Principle:
Principle #3Local quality

3Power

If conventional emitting materials are used, then device operation is achieved, but operating voltage remains high

Engineering Contradiction:
Improveoperating voltageVSAvoiddevice efficiency
Core Design Contradiction:
PowerVSProductivity

Solution Approach 1:

The patent designs emitting materials with dynamic molecular characteristics that facilitate efficient charge injection and transport. The heterocyclic structures provide flexible electron delocalization pathways that adapt to electric field conditions, enabling lower operating voltages while maintaining high electroluminescence efficiency through optimized charge carrier dynamics

Inventive Principle:
Principle #15Dynamics

4Ease of manufacture

If existing compounds are used in electroluminescent devices, then device function is achieved, but processability and solubility are insufficient

Engineering Contradiction:
ImproveprocessabilityVSAvoidsolubility
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

The patent segments the emitting material molecules by introducing distinct functional domains: core heterocyclic structures for optical properties and peripheral substituents (alkyl chains, aryl groups) for solubility enhancement. This segmentation allows independent optimization of processability through solubility control while preserving the core molecular functions for efficient electroluminescence

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these heterocyclic compounds leads to organic electroluminescence devices with improved lifespan, color purity, efficiency, and reduced operating voltage, while maintaining excellent processability and solubility.

Implementation Method 1

organic electroluminescent materials

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP4423209B1Boronic and nitrogenous heterocyclic compounds for organic electroluminescent devices
Publication Date: 2025.05.07 MERCK PATENT GMBH
  • EP4423209B1 patent drawing
  • EP4423209B1 patent drawing
  • EP4423209B1 patent drawing

AI summary

The present invention relates to boronic and nitrogenous heterocyclic compounds that are suitable for use in electronic devices, and to electronic devices, in particular organic electroluminescent devices, containing said compounds.