Borosilicate Glass and Barite Shielding Material for Radiation

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Solution Overview

Problem

Current shielding materials for radioactive rays, such as concrete, face challenges in achieving high density and homogeneity while maintaining structural strength, fire resistance, and minimizing shrinkage, especially when shielding against gamma and neutron radiation, which requires a balance of light and heavy elements and adequate water content.

Innovation Solution

A shielding material composed of water, Portland cement, borosilicate glass powder, barite sand, and barite as coarse aggregate, with specific proportions of boron and barium sulfate, along with additives like a polycarboxylic water reducer, to achieve a density range of 3.46 to 3.55 g/cm3, providing effective neutron and gamma ray shielding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If concrete shielding material is used to shield gamma and neutron radiation, then radiation shielding capability is improved, but density and homogeneity are difficult to achieve while maintaining structural strength

Engineering Contradiction:
Improveradiation shielding capabilityVSAvoidstructural strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent uses composite materials by combining barite (heavy element for gamma shielding), borosilicate glass powder (light element for neutron shielding), and Portland cement as binding agent. This composite approach allows simultaneous achievement of radiation shielding capability and structural strength through synergistic material combination

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by using barite as coarse aggregate (10-40mm) and barite sand as fine aggregate (0.075-4.75mm), creating different density zones within the concrete matrix. The heavy barite particles are strategically distributed to provide localized gamma shielding, while the borosilicate glass powder provides uniform neutron shielding throughout the matrix

Inventive Principle:
Principle #3Local quality

2Object-affected harmful factors

If high density shielding material is used to shield radiation, then shielding effectiveness is improved, but shrinkage and homogeneity issues worsen

Engineering Contradiction:
Improveshielding effectivenessVSAvoidshrinkage and homogeneity
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The patent optimizes parameter ratios including water-cement ratio (0.37), sand ratio (32.1%), and additive dosage (1.80%) to balance density achievement with shrinkage control. The polycarboxylic water reducer adjusts the water-cement ratio to maintain workability while achieving high density without excessive shrinkage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The polycarboxylic water reducer acts as an intermediary substance that improves the compatibility between water and cement, reducing capillary pores and micro-cracks. This mediator enhances homogeneity and reduces shrinkage while allowing the high-density barite aggregates to be properly distributed and embedded

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If adequate water content is added to improve neutron shielding, then neutron shielding capability is improved, but construction workability and structural strength are affected

Engineering Contradiction:
Improveneutron shielding capabilityVSAvoidconstruction workability
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The polycarboxylic water reducer serves as a mediator that allows adequate water content to be present for neutron shielding while maintaining construction workability. It reduces surface tension and improves fluidity, enabling the mix to remain workable with higher water content necessary for hydrogen-rich neutron shielding

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the water-cement ratio parameter to 0.37, which provides sufficient water for neutron shielding capability while the polycarboxylic water reducer maintains workability. This parameter optimization balances the competing requirements of neutron shielding and construction ease

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The material offers excellent performance in shielding neutron and gamma rays, is cost-effective, and requires a compatible thickness, ensuring effective radiation protection with improved mechanical properties and constructability.

Implementation Method 1

barium sulfate content in the barite sand and the barite accounts for 71 to 75 percent of the total weight of the shielding material

Methodology Applied
Scientific EffectPhotoelectric absorption: Absorption (EM radiation)

Implementation Method 2

The γ ray is a type of electromagnetic waves with high energy and high frequency, and has enormous penetrability. As they penetrate a protective substance, they can be absorbed gradually

Methodology Applied
Scientific EffectCompton scattering: Compton Scattering

Implementation Method 3

boron element content in the borosilicate glass powder accounts for 0.5 to 1 percent of the total weight of the shielding material; nuclei can only capture and absorb the slow neutrons

Methodology Applied
Scientific EffectNeutron capture: Absorption (physical)

Implementation Method 4

the rapid neutrons can only be decelerated by colliding with nuclei, but when the nuclei of certain substances collide with the neutrons, secondary γ ray will be generated. The intermediate neutrons can be decelerated by the nuclei of light elements

Methodology Applied
Scientific EffectElastic collision: Conservation of Momentum

Implementation Method 5

a cementing material, fine aggregate, coarse aggregate and an additive, wherein the fine aggregate is composed of borosilicate glass powder and barite sand

Methodology Applied
Scientific EffectHydraulic setting: Chemical Bonding

Data Source

PatentUS10636534B2Shielding material for shielding radioactive ray and preparation method thereof
Publication Date: 2020.04.28 NEUBORON MEDTECH LTD
  • US10636534B2 patent drawing
  • US10636534B2 patent drawing

AI summary

A shielding material for shielding radioactive ray and preparation method thereof. The shielding material consists of water, a cementing material, a fine aggregate material, a coarse aggregate material and an additive, wherein the fine aggregate material consists of a borosilicate glass powder and a barite sand, and the coarse aggregate material consists of a barite. A content of boron element in the borosilicate glass powder accounts for 0.5%-1% of the total weight of the shielding material. A content of barium sulfate in the barite sand and the barite accounts for 71%-75% of the total weight of the shielding material. Other contents include water, the cementing material and the additive, and a sum of contents of all components is 100% total weight of the shielding material.