Bottle Preform Moisture Conditioning for Reproducible Crystallization

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Solution Overview

Problem

Existing methods for manufacturing aerosol bottles from thermoplastic materials fail to consistently achieve the desired mechanical characteristics, particularly for bottles containing liquefied propellant gases, due to inconsistent crystallization processes.

Innovation Solution

A method involving moisture uptake of injection-molded articles, specifically preforms, to a weight percentage of at least 0.4% before crystallization, followed by controlled heating and cooling to achieve a crystallinity gradient, enhancing thermal conductivity and mechanical strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If heat treatment is applied to crystallize the neck part of the preform, then mechanical strength is improved, but the crystallization process is not reproducible and desired mechanical characteristics are not consistently achieved

Engineering Contradiction:
Improvemechanical strengthVSAvoidreproducibility
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The preform is pre-conditioned by controlling moisture content before the crystallization heat treatment. This preliminary action ensures that the material is in the optimal state to receive the heat treatment, making the subsequent crystallization process reproducible and reliable.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention changes the physical-chemical parameters of the polymer material by controlling moisture content (0.5-5% by weight) before heat treatment. This parameter adjustment enables reproducible crystallization and consistent mechanical properties.

Inventive Principle:
Principle #35Parameter changes

2Weight of moving object

If the preform is made lighter through crystallization, then weight is reduced, but the crystallization process must be precisely controlled to achieve consistent results

Engineering Contradiction:
Improvebottle weightVSAvoidcrystallization control
Core Design Contradiction:
Weight of moving objectVSManufacturing precision

Solution Approach 1:

Moisture content is controlled in advance before crystallization, preparing the material to achieve consistent crystallization results with reduced weight and improved mechanical properties.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

By adjusting the moisture content parameter to specific ranges (0.5-5% by weight), the crystallization process becomes more controllable and reproducible, enabling consistent lightweight bottle production.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method ensures reproducible and improved mechanical properties, allowing aerosol bottles to withstand high pressures and temperatures, ensuring safety and performance.

Implementation Method 1

the injection-molded article, in particular the injection-molded preform, is held for a sufficient duration under storage conditions such that it undergoes moisture uptake of at least 0.4%, better still at least 0.8%, and even better still at least 1%, by weight

Methodology Applied
Scientific EffectMoisture uptake: Absorption (physical)

Implementation Method 2

The invention is based on the finding that such moisture uptake makes it possible to improve the thermal conductivity of the material of the article

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

crystallizing said part of the injection-molded article, in particular of the injection-molded preform, by heating and then cooling the latter

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 4

the plastic material is subjected to a crystallizing heat treatment in the region of said neck

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 5

the heat treatment, which is effected for example with the aid of lamps emitting infrared radiation

Methodology Applied
Scientific EffectInfrared radiation: Infrared Radiation

Implementation Method 6

lamps emitting infrared radiation

Methodology Applied
Scientific EffectThermal radiation: Thermal Radiation

Data Source

PatentUS12390969B2Method for manufacturing an injection-molded article, in particular a bottle preform
Publication Date: 2025.08.19 LOREAL SA
  • US12390969B2 patent drawing
  • US12390969B2 patent drawing
  • US12390969B2 patent drawing

AI summary

A method for manufacturing an injection-molded article, preferably a preform (11) of a bottle (1), in particular an aerosol bottle, made of a crystallizable polymer material, this article having at least one crystallized part (3), in particular a neck, and preferably a tubular body (14) closed at one end (16), the method comprising the following steps: a) producing an injection-molded article, preferably an injection-molded preform (11), by injecting the crystallizable polymer into a mold, b) crystallizing said part (3) of the injection-molded article, in particular of the injection-molded preform, by heating and then cooling the latter, wherein, in said method, between step a) and step b), the injection-molded article, in particular the injection-molded preform (11), is held for a sufficient duration under storage conditions such that it undergoes moisture uptake of at least 0.4% by weight.