Bottom Isolation Formation via Selective Fluorine Plasma Etching

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Solution Overview

Problem

Conventional semiconductor processing methods face challenges in forming high-quality semiconductor structures with effective current leakage prevention and defect-free source/drain formation, often requiring reactive-ion etching (RIE) and ion implantation operations that can damage substrates and introduce defects.

Innovation Solution

A method involving selective etching and deposition processes in a remote plasma system, forming a bottom insulation layer without extending into source or drain regions, using a fluorine-containing precursor plasma to recess silicon-containing materials and deposit spacer materials selectively, thereby avoiding RIE and ion implantation operations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional RIE and ion implantation operations are used to form bottom insulation layer, then current leakage prevention is improved, but substrate damage and defect introduction increase

Engineering Contradiction:
Improvecurrent leakage preventionVSAvoidsubstrate damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the etching parameters by using a remote plasma source with fluorine-containing precursors instead of conventional RIE, and controls the etching conditions to achieve selective removal of silicon-containing materials without damaging the substrate. This parameter change allows effective current leakage prevention while minimizing substrate damage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a remote plasma source as an intermediary between the etching chemistry and the substrate. The remote plasma generates fluorine-containing species that selectively etch silicon-containing materials without direct ion bombardment, thus preventing substrate damage while still forming the bottom insulation layer effectively

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If selective etching and deposition processes are used in remote plasma system, then substrate damage is reduced, but process complexity increases

Engineering Contradiction:
Improvesubstrate damageVSAvoidprocess complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent combines selective etching and deposition processes into a unified remote plasma system workflow. By integrating these processes and using automated sequence control, the system manages complexity while maintaining the benefits of reduced substrate damage through selective material removal and spacer formation

Inventive Principle:
Principle #5Merging (Combining)

3Manufacturing precision

If conventional masking and removal operations are performed, then manufacturing precision is improved, but process queue time increases

Engineering Contradiction:
Improvepattern transfer accuracyVSAvoidprocess queue time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent extracts and eliminates unnecessary masking and removal operations from the conventional process sequence. By using selective etching that inherently defines the desired patterns without requiring additional masking steps, the process achieves comparable manufacturing precision while significantly reducing process queue time

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively prevents current leakage through bottom nanowire channels without hindering source or drain formation, reduces defects, and minimizes damage to substrates, while also reducing process queue times by eliminating unnecessary masking and removal operations.

Implementation Method 1

forming a plasma of a fluorine-containing precursor in a remote plasma region of a processing chamber

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

contacting a semiconductor substrate with effluents of the plasma... The layers of the third silicon-containing material may be selectively recessed relative to the layer of the first silicon-containing material

Methodology Applied
Scientific EffectChemical etching:

Implementation Method 3

depositing a spacer material adjacent to the layers of the third silicon-containing material... The spacer material may be selectively deposited adjacent to the layers of the third silicon-containing material relative to exposed regions of the layer of the first silicon-containing material

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 4

etching the layer of the first silicon-containing material... The layer of the first silicon-containing material may be selectively etched relative to the layers of the second silicon-containing material and the spacer material

Methodology Applied
Scientific EffectChemical etching:

Data Source

PatentUS11348803B2Formation of bottom isolation
Publication Date: 2022.05.31 APPLIED MATERIALS INC
  • US11348803B2 patent drawing
  • US11348803B2 patent drawing
  • US11348803B2 patent drawing

AI summary

A method may include forming a plasma of a fluorine-containing precursor and contacting a semiconductor substrate with plasma effluents. The semiconductor substrate may include a layer of a first silicon-containing material having a first germanium content formed over the semiconductor substrate, and alternating layers of a second silicon-containing material and a third silicon-containing material over the layer of the first silicon-containing material. The third silicon-containing material may have a second germanium content. The method may further include laterally recessing the third silicon-containing material relative to the first and second silicon-containing materials. The method may further include depositing a spacer material adjacent to the third silicon-containing material relative to the first and second silicon-containing materials. The method may also include etching the first silicon-containing material relative to the second silicon-containing material and the spacer material.