Branched Alcohol Foam Control for Stable Metalworking Fluids

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Solution Overview

Problem

Metal working fluids (MWFs) face issues with excessive foam generation due to surfactants, leading to insufficient lubricity and liquid overflow, which existing silicone-based foam control agents fail to adequately address due to instability and biodegradability concerns, as well as surface deposition affecting finishing processes.

Innovation Solution

A foam control agent comprising branched alcohols, such as 2-ethylhexanol and 2-propylheptanol, which are synthesized via aldol condensation or the Guerbet reaction, offering superior foam control performance and stability in various MWF formulations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If silicone-based foam control agents are used to reduce foaming, then foam control performance is improved, but biodegradability deteriorates and stability in MWF formulations worsens

Engineering Contradiction:
Improvefoam generationVSAvoidstability in MWF formulations
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the foam control agent by using branched alcohols with specific carbon chain lengths (C8-C22) and specific branching structures (2-alkyl-1-alkanols), which fundamentally alters the agent's properties to achieve both effective foam control and improved stability and biodegradability compared to silicone-based agents

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces expensive, persistent silicone-based foam control agents with more readily biodegradable branched alcohol compounds, effectively using a shorter-lived, environmentally friendlier substance that breaks down more easily while still performing the foam control function

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-generated harmful factors

If silicone-based foam control agents are used to reduce foaming, then foam control performance is improved, but deposition on metal surfaces increases, affecting finishing quality

Engineering Contradiction:
Improvefoam generationVSAvoidsurface finishing quality
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The patent changes the surface activity parameters of the foam control agent by selecting branched alcohols with specific hydrophobicity and surface tension characteristics, which reduces their tendency to deposit on metal surfaces while maintaining foam control effectiveness, thereby preserving surface finishing quality

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If surfactants are added to provide lubricity, then lubrication performance is improved, but foam generation increases

Engineering Contradiction:
ImprovelubricityVSAvoidfoam generation
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a branched alcohol foam control agent as an intermediary substance that specifically targets and eliminates foam without interfering with the lubrication function of surfactants, allowing both lubricity and foam control to coexist in the metal working fluid formulation

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The branched alcohol-based foam control agents effectively reduce foaming in MWFs, maintaining lubricity and transparency, and are biodegradable, outperforming traditional silicone defoamers in stability and performance across different metal working fluid types.

Implementation Method 1

Silicone based foam control agents are widely used in MWFs to address the foaming issue due to these agents very low surface tension

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Implementation Method 2

The branched alcohol-based foam control agents effectively reduce foaming in MWFs

Methodology Applied
Scientific EffectFoam control: Foam

Data Source

PatentUS12116544B2Metal working fluids foam control agent
Publication Date: 2024.10.15 DOW GLOBAL TECHNOLOGIES LLC
  • US12116544B2 patent drawing
  • US12116544B2 patent drawing
  • US12116544B2 patent drawing

AI summary

A foam control agent and method of controlling foam for metal working fluids by use of a foam control agent, wherein the agent comprises at least a branched alcohol.