Branched Poly(Hydroxyacid) Downhole Tool Members for Faster Degradation

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Solution Overview

Problem

Existing downhole tools used for hydrocarbon extraction are not designed to be retrievable and require significant time and cost for removal, and linear poly(glycolic acid) polymers have a slow thickness reduction rate in water, limiting their effectiveness.

Innovation Solution

The use of branched poly(hydroxyacid) polymers, formed through specific polycondensation reactions, which exhibit a higher thickness reduction rate in water over time, allowing for efficient decomposition in situ.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If linear poly(glycolic acid) polymers are used for downhole tool members, then the tool members are biodegradable and can decompose in the ground, but the thickness reduction rate in water is slow, limiting decomposition efficiency

Engineering Contradiction:
ImprovebiodegradabilityVSAvoidthickness reduction rate
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the molecular architecture parameter from linear to branched structure. This structural parameter change significantly accelerates the degradation rate while maintaining biodegradability. The branched structure creates more chain ends and increases surface area exposure to water, facilitating faster hydrolysis and thickness reduction.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite polymer system by combining poly(glycolic acid) units with poly(lactic acid) units in a copolymer structure. This composite approach leverages the synergistic degradation properties of both polymer types, achieving faster thickness reduction rates while maintaining complete biodegradability in the downhole environment.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If downhole tools are made non-retrievable to simplify design, then manufacturing and operation are easier, but significant time and cost are required for removal through milling or drill out

Engineering Contradiction:
Improvetool design simplicityVSAvoidremoval time
Core Design Contradiction:
Ease of manufactureVSLoss of time

Solution Approach 1:

The patent implements a disposable downhole tool concept where the entire tool is constructed from biodegradable polymers. After completing its function, the tool automatically degrades in situ through hydrolysis and microbial action, eliminating the need for costly and time-consuming retrieval operations. This transforms the tool from a permanent component to a temporary, self-destructing device.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The downhole tool performs self-service by automatically decomposing itself after use. The biodegradable polymer material inherently contains the degradation mechanism within its molecular structure, requiring no external intervention for removal. The tool self-digests through hydrolytic cleavage and microbial degradation, converting itself into harmless byproducts that can be naturally disposed of in the formation.

Inventive Principle:
Principle #25Self-service

3Ease of operation

If downhole tools are made non-retrievable to simplify operation, then ease of operation is improved, but substantial cost is required for milling, drill out, or other removal methods

Engineering Contradiction:
Improveoperation simplicityVSAvoidremoval cost
Core Design Contradiction:
Ease of operationVSLoss of energy

Solution Approach 1:

The patent applies the disposable tool concept by using biodegradable polymers that eliminate retrieval costs entirely. The tool is designed to be cheap enough to leave in the formation, as its automatic degradation eliminates all removal expenses. This transforms the economic model from expensive permanent tools requiring retrieval infrastructure to inexpensive temporary tools that self-eliminate.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent converts what would traditionally be considered waste (the discarded tool) into a beneficial process. The degradation of the tool material releases breakdown products that can serve as nutrients for formation microorganisms, potentially stimulating microbial activity that benefits hydrocarbon production. The 'harm' of leaving a tool in the formation becomes the 'benefit' of controlled biodegradation and potential formation stimulation.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The branched poly(hydroxyacid) polymers provide a faster degradation rate, reducing the need for costly and time-consuming removal processes and enhancing the efficiency of downhole tool operations.

Implementation Method 1

the branched poly(hydroxyacid) polymers provide a faster degradation rate, reducing the need for costly and time-consuming removal processes

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS12384878B2Downhole tool member comprising a branched poly(hydroxyacid)
Publication Date: 2025.08.12 SOLVAY SPECIALTY POLYMERS USA LLC
  • US12384878B2 patent drawing

AI summary

The invention relates to downhole tools comprising members comprising branched poly(hydroxyacid) polymers provided with improved degradation rate when in contact with water.