Branched Sulphonated Multi Block Copolymer Fuel Cell Membrane

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current polymer electrolyte membranes for fuel cells face challenges in achieving high proton conductivity, mechanical stability, and cost-effectiveness, with limitations in regulating sulfonic acid group distribution and number, leading to decreased properties at increased sulfonic acid content and complex production processes.

Innovation Solution

A branched and sulphonated multi block copolymer with specific repeating units is developed, comprising hydrophobic and hydrophilic blocks, allowing for controlled sulfonation and hydrogenation to create a membrane with high proton conductivity and mechanical integrity, produced through polymerization and solution pouring methods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the number of sulfonic acid groups is increased to improve proton conductivity, then proton conductivity is improved, but mechanical properties and chemical stability deteriorate

Engineering Contradiction:
Improveproton conductivityVSAvoidmechanical properties
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies local quality by creating distinct hydrophobic blocks and hydrophilic blocks with different functions. The hydrophobic blocks (containing sulfonic acid groups) provide proton conductivity locally, while the hydrophilic blocks maintain mechanical integrity and chemical stability. This spatial separation of functions allows the membrane to achieve high proton conductivity without sacrificing mechanical properties.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining hydrophobic blocks (with sulfonic acid groups for proton conduction) and hydrophilic blocks (for mechanical strength and stability) into a multi-block copolymer structure. This composite approach enables the membrane to simultaneously achieve high proton conductivity and maintain excellent mechanical properties, resolving the contradiction between these two requirements.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the number of sulfonic acid groups is increased to improve proton conductivity, then proton conductivity is improved, but chemical stability deteriorates

Engineering Contradiction:
Improveproton conductivityVSAvoidchemical stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by concentrating sulfonic acid groups in specific hydrophobic blocks while maintaining hydrophilic blocks that provide chemical stability. This localized distribution allows high proton conductivity in the hydrophobic regions while the hydrophilic regions maintain overall chemical stability of the membrane structure.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The composite multi-block copolymer structure combines hydrophobic blocks (providing proton conductivity through sulfonic acid groups) with hydrophilic blocks (providing chemical stability). This composite design enables the membrane to achieve high proton conductivity without compromising chemical stability, as the hydrophilic blocks protect the overall structure from degradation.

Inventive Principle:
Principle #40Composite materials

3Reliability

If post-sulfonation method is used to increase sulfonic acid groups, then proton conductivity is improved, but regulation of sulfonic acid group distribution and location becomes difficult

Engineering Contradiction:
Improveproton conductivityVSAvoidregulation of sulfonic acid group distribution
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by incorporating sulfonic acid groups into the polymer structure during the polymerization step, before the membrane formation process. This allows precise control over the distribution and location of sulfonic acid groups within the hydrophobic blocks, enabling regulated placement rather than random post-sulfonation modification.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses segmentation by dividing the polymer into distinct hydrophobic blocks (containing sulfonic acid groups) and hydrophilic blocks. This segmentation allows independent control and regulation of sulfonic acid group distribution within the hydrophobic blocks, achieving precise manufacturing control over their location and concentration.

Inventive Principle:
Principle #1Segmentation

4Stability of the object's composition

If perfluorinated polymer electrolyte is used to achieve chemical stability and mechanical properties, then chemical stability and mechanical properties are improved, but cost increases

Engineering Contradiction:
Improvechemical stabilityVSAvoidcost
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The patent applies this principle by using hydrocarbon-based polymers (cheaper materials) instead of expensive perfluorinated polymers. While hydrocarbon polymers may have shorter operational lifespan, the multi-block copolymer structure with controlled sulfonic acid group distribution compensates for this, providing adequate chemical stability and mechanical properties at lower cost, making it economically viable for fuel cell applications.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent uses composite materials by combining hydrocarbon-based hydrophobic blocks with hydrophilic blocks to create a multi-block copolymer that mimics the performance of perfluorinated polymers. This composite approach achieves comparable chemical stability and mechanical properties using cheaper hydrocarbon materials, reducing cost while maintaining necessary performance characteristics.

Inventive Principle:
Principle #40Composite materials

5Reliability

If complex production process is used to achieve high proton conductivity and mechanical properties, then membrane performance is improved, but production complexity increases

Engineering Contradiction:
Improvemembrane performanceVSAvoidproduction complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by incorporating the sulfonic acid groups and forming the multi-block structure during the polymerization step itself. This preliminary incorporation eliminates the need for separate post-sulfonation steps and complex processing, simplifying the overall production process while maintaining high membrane performance through the controlled multi-block architecture.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent merges multiple functions into a single polymerization step, where the multi-block copolymer structure with sulfonic acid groups is formed in one process. This merging of polymerization and functional group incorporation simplifies production by eliminating separate steps for structure formation and sulfonation, reducing production complexity while achieving high membrane performance.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting membrane exhibits excellent proton conductivity, mechanical properties, and chemical stability, enabling efficient fuel cell operation while maintaining membrane integrity and reducing production complexity.

Implementation Method 1

a branched and sulphonated multi block copolymer which has high level of proton conductivity and excellent mechanical properties

Methodology Applied
Scientific EffectSulfonation: Chemical Bonding

Implementation Method 2

a hydrogenated branched and sulphonated multi block copolymer

Methodology Applied
Scientific EffectHydrogenation: Hydrogenation

Data Source

PatentUS7807759B2Branched and sulphonated multi block copolymer and electrolyte membrane using the same
Publication Date: 2010.10.05 LG CHEM LTD
  • US7807759B2 patent drawing
  • US7807759B2 patent drawing
  • US7807759B2 patent drawing

AI summary

The present invention relates to a branched and sulphonated multi block copolymer and an electrolyte membrane using the same, more precisely, a branched and sulphonated multi block copolymer composed of the repeating unit represented by formula 1 and a preparation method thereof, a hydrogenated branched and sulphonated multi block copolymer, a branched and sulphonated multi block copolymer electrolyte membrane and a fuel cell to which the branched and sulphonated multi block copolymer electrolyte membrane is applied.The electrolyte membrane of the present invention has high proton conductivity and excellent mechanical properties as well as chemical stability, so it can be effectively used for the production of thin film without the decrease of membrane properties according to the increase of sulfonic acid group since it enables the regulation of the distribution, the location and the number of sulfonic acid group in polymer backbone.