Braze Material with Surface-Embedded Melt Modifiers

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Solution Overview

Problem

Brazing of certain superalloys is hindered by the tendency of melting point depressants to form embrittling phases, leading to segregation issues and detrimental effects on mechanical properties, and existing microwave brazing techniques face challenges in localized heating and heat loss.

Innovation Solution

A braze material comprising particles with melt-modifying constituents, such as melting point depressants and microwave coupling enhancers, are embedded in the outer surface region of the particles, allowing for controlled melting and improved heating rates through conventional or microwave radiation, while maintaining the mechanical properties of the brazement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If melting point depressants are added to braze alloy to enable brazing of superalloys, then brazing becomes possible, but embrittling phases form and mechanical properties deteriorate

Engineering Contradiction:
Improvebrazing capabilityVSAvoidmechanical properties
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The braze alloy is segmented into multiple powder sizes: coarse powder containing the base superalloy composition and fine powder containing the melting point depressants. This segmentation prevents the fine depressant particles from segregating to the brazement surface while still enabling them to form eutectics and facilitate brazing, thus avoiding embrittling phase formation and maintaining mechanical properties.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention applies local quality by concentrating melting point depressants in the fine powder fraction that remains distributed within the brazement structure, while the coarse powder provides the bulk mechanical properties. This localized distribution ensures depressants are present where needed for brazing without overwhelming the overall structure with embrittling phases.

Inventive Principle:
Principle #3Local quality

2Strength

If two powders with different compositions are used to control melting point depressant distribution, then mechanical properties are maintained, but powder segregation occurs during brazing

Engineering Contradiction:
Improvemechanical propertiesVSAvoidpowder distribution
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The braze material is segmented into coarse and fine powder fractions with different compositions. The fine powder containing melting point depressants is designed to remain dispersed within the brazement structure due to its size, preventing segregation while maintaining composition control and mechanical properties.

Inventive Principle:
Principle #1Segmentation

3Productivity

If microwave coupling enhancers are added to braze powder to improve microwave heating, then heating rate increases, but excessive enhancers cause property losses

Engineering Contradiction:
Improveheating rateVSAvoidbrazement properties
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

Microwave coupling enhancers are concentrated in the fine powder fraction rather than being uniformly distributed. This local concentration provides sufficient microwave absorption to enable rapid heating and melting of the braze material, while the overall low volume of enhancers prevents detrimental effects on brazement mechanical properties.

Inventive Principle:
Principle #3Local quality

4Ease of manufacture

If conventional brazing is used to join superalloy components, then manufacturing is achieved, but heat loss and lack of localized heating occur

Engineering Contradiction:
Improvemanufacturing capabilityVSAvoidheat loss
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The invention replaces conventional thermal conduction-based heating with microwave electromagnetic field heating. The fine powder fraction containing microwave coupling enhancers absorbs microwave energy efficiently, enabling rapid and localized heating of the braze material without significant heat loss to the surrounding superalloy components.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the mechanical properties of brazements, promotes broader use of brazing processes, and improves heating efficiency, particularly in gas turbine engine components, by ensuring localized melting and reduced segregation of melt-modifying constituents.

Implementation Method 1

heating a braze material, typically in the form of a braze alloy powder... to a temperature above the melting point of the braze alloy

Methodology Applied
Scientific EffectMicrowave radiation heating: Microwave Radiation

Implementation Method 2

a second approach entails direct microwave heating of a braze alloy powder, which is more susceptible to absorbing microwave energy than bulk metals

Methodology Applied
Scientific EffectDielectric heating: Dielectric Heating

Implementation Method 3

the braze alloy will typically have a composition essentially or nearly the same as the substrate, but modified to contain one or more melting point suppressants, such as boron and/or silicon, which form low melting eutectics with the substrate material

Methodology Applied
Scientific EffectMelting point depression:

Implementation Method 4

melting point suppressants, such as boron and/or silicon, which form low melting eutectics with the substrate material

Methodology Applied
Scientific EffectEutectic formation:

Data Source

PatentUS7946467B2Braze material and processes for making and using
Publication Date: 2011.05.24 GENERAL ELECTRIC CO
  • US7946467B2 patent drawing
  • US7946467B2 patent drawing
  • US7946467B2 patent drawing

AI summary

A braze material and processes for making and using the material, such as for use in the manufacturing, coating, repair, and build-up of superalloy components. The braze material is composed of particles with melt-modifying constituents that are limited to the surfaces of the particles, yet are capable of sufficiently promoting the heating of the particles by conventional means and microwave radiation to achieve at least partial melting of the particles. The melt-modifying constituents are in the form of particulates embedded in the outer surface region of each particle. The particulates are formed of melting point depressant(s) and/or microwave coupling enhancer(s), are much smaller than the particle in which they are embedded.