Brazed Aluminum Strip Interlayer for Corrosion and Core Penetration

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Solution Overview

Problem

Current materials for brazed heat exchangers face challenges in achieving high post-braze strength combined with excellent corrosion resistance and resistance to liquid core penetration, especially when using thinner strips, which is crucial for weight reduction in automotive applications.

Innovation Solution

A corrosion-resistant strip is developed with a core and an interlayer composition that includes specific elements like Mn, Si, and Cu, where the interlayer has a controlled texture component and grain size, and is processed to minimize recrystallization during brazing, resulting in a strip that is highly resistant to liquid core penetration and maintains formability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of moving object

If thinner strip materials are used to reduce weight, then weight is reduced, but post-braze strength and corrosion resistance deteriorate

Engineering Contradiction:
Improveweight of heat exchangerVSAvoidpost-braze strength
Core Design Contradiction:
Weight of moving objectVSStrength

Solution Approach 1:

The strip is segmented into multiple functional layers: a core material providing structural strength and an intermediate layer providing corrosion resistance and controlling liquid core penetration. This segmentation allows each layer to be optimized for its specific function, enabling thinner overall thickness while maintaining strength and corrosion resistance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite structure combining different aluminum alloys in the core and intermediate layer. The core uses an Al-Mn-Si alloy for strength, while the intermediate layer uses a different composition optimized for corrosion resistance and brazing performance. This composite approach allows the thin strip to achieve properties that neither material could provide alone.

Inventive Principle:
Principle #40Composite materials

2Weight of moving object

If thinner strip materials are used to reduce weight, then weight is reduced, but corrosion resistance deteriorates

Engineering Contradiction:
Improveweight of heat exchangerVSAvoidcorrosion resistance
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The strip is segmented into multiple functional layers: a core material providing structural strength and an intermediate layer providing corrosion resistance and controlling liquid core penetration. This segmentation allows each layer to be optimized for its specific function, enabling thinner overall thickness while maintaining strength and corrosion resistance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the strip are given different compositions and properties: the core has properties optimized for strength, while the intermediate layer has properties optimized for corrosion resistance and brazing. This local differentiation of material properties allows the thin strip to achieve superior overall performance.

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If conventional materials are used, then manufacturing is simple, but resistance to liquid core penetration deteriorates

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidresistance to liquid core penetration
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention changes the compositional parameters of the intermediate layer, specifically controlling Si, Mn, Mg, and Fe content within precise ranges. These parameter changes create an intermediate layer that is resistant to liquid core penetration while maintaining ease of manufacture through conventional rolling and brazing processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite structure combining different aluminum alloys in the core and intermediate layer. The core uses an Al-Mn-Si alloy for strength, while the intermediate layer uses a different composition optimized for corrosion resistance and brazing. This composite approach allows the thin strip to achieve properties that neither material could provide alone.

Inventive Principle:
Principle #40Composite materials

4Strength

If high post-braze strength is achieved through material alloying, then strength is improved, but corrosion resistance deteriorates

Engineering Contradiction:
Improvepost-braze strengthVSAvoidcorrosion resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The strip is segmented into multiple functional layers: a core material providing structural strength and an intermediate layer providing corrosion resistance and controlling liquid core penetration. This segmentation allows each layer to be optimized for its specific function, enabling thinner overall thickness while maintaining strength and corrosion resistance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite structure combining different aluminum alloys in the core and intermediate layer. The core uses an Al-Mn-Si alloy for strength, while the intermediate layer uses a different composition optimized for corrosion resistance and brazing. This composite approach allows the thin strip to achieve properties that neither material could provide alone.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The strip achieves superior post-braze corrosion properties, high strength, and excellent brazing performance with low susceptibility to liquid core penetration, enabling the use of thinner materials while maintaining product integrity.

Implementation Method 1

the interlayer is pre-heated to a temperature of 380-520°C prior to hot rolling so as to form dispersoid particles in the interlayer

Methodology Applied
Scientific EffectRecrystallization:

Implementation Method 2

heat treating the cold rolled strip to the delivery temper with the purpose to soften the material by a tempering without any recrystallisation of the interlayer

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 3

The lower corrosion potential on the surface is due to the existence of more manganese and copper in solid solution in the core centre than in the core surface. This is due to diffusion of especially silicon and copper between the core and the braze clad

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 4

The joints form by capillary flow of the filler metal to the desired joint sites and solidify to form a solid metallic connection between individual components

Methodology Applied
Scientific EffectBrazing: Brazing

Implementation Method 5

The joints form by capillary flow of the filler metal to the desired joint sites

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Data Source

PatentEP2877317B2Strip material with excellent corrosion resistance after brazing
Publication Date: 2022.07.27 GRAENGES SWEDEN AB
  • EP2877317B2 patent drawingFigure 1a~2c
  • EP2877317B2 patent drawingFigure 3a~4
  • EP2877317B2 patent drawingFigure 5

AI summary

A corrosion resistant strip is disclosed. The strip comprises a core, and an interlayer adapted to be located between the core and an optional Al-Si based clad. The interlayer has a composition essentially consisting of (in percentages by weight): Si≤0.9%, Fe≤0.7%, Cu≤0.5%, Mn0.5-1.8%, Mg≤0.7%, Zn≤4.0%, Ni≤1.5%, elements selected from group IVb, Vb, and/or VIb of the periodic table ≤0.3% each and ≤0.5% in total ≤0.05 wt% each and ≤0.15 % in total, of unavoidable impurity elements, balance Al. The core is more noble than the interlayer after brazing. The interlayer exhibits a volume fraction of a texture component of at least 30%.