Bromine-Based Oxidizing Agent Filtration System

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Solution Overview

Problem

Current filtration treatment systems require complex steps and generate significant washing wastewater when treating water with organic substances, as they need to use oxidizing agents like hypochlorous acid, which can degrade reverse osmosis membranes and require additional agents for slime control and wastewater neutralization.

Innovation Solution

A filtration treatment system that uses a bromine-based oxidizing agent or its reaction products with chlorine-based agents and sulfamic acid, applied under an inert gas atmosphere, to simplify the treatment process and reduce wastewater by inhibiting slime generation and membrane degradation without the need for additional agents or extensive flushing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an oxidizing agent such as hypochlorous acid is added to the raw water or backwash water for slime control, then slime generation is inhibited, but residual oxidizing agent degrades the reverse osmosis membrane

Engineering Contradiction:
Improveslime control effectivenessVSAvoidmembrane degradation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameter by using bromine-based oxidizing agents instead of chlorine-based hypochlorous acid. Bromine compounds provide effective slime control while being less harmful to polyamide reverse osmosis membranes, thus resolving the contradiction between slime inhibition and membrane protection

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces activated carbon as an intermediary substance that removes residual oxidizing agents before they reach the reverse osmosis membrane. The activated carbon column acts as a buffer that protects the membrane from direct contact with harmful oxidizing agents while maintaining slime control benefits

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If additional treatment steps (activated carbon column, reducing agent addition) are added to remove residual oxidizing agents, then membrane degradation is prevented, but system complexity increases

Engineering Contradiction:
Improvemembrane degradation preventionVSAvoidtreatment system complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent extracts and removes the harmful residual oxidizing agents using an activated carbon column positioned between the oxidizing agent injection point and the reverse osmosis membrane. This separation allows the system to maintain slime control while protecting the membrane, balancing complexity and protection needs

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If a chemical agent cleaning step is performed to remove accumulated impurities, then membrane performance is restored, but washing wastewater is generated

Engineering Contradiction:
Improvemembrane performance restorationVSAvoidwashing wastewater generation
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent implements a flushing step that recovers and reuses the washing water containing dissolved impurities. Instead of discarding the wastewater, it is collected and can be treated or reused, reducing overall water consumption and wastewater generation while maintaining effective membrane cleaning

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively reduces the complexity of treatment steps and minimizes washing wastewater while preventing slime generation and membrane degradation, allowing for stable operation of polyamide reverse osmosis membranes without the need for additional reducing agents or activated carbon.

Implementation Method 1

a bromine-based oxidizing agent, or a reaction product of a bromine compound and a chlorine-based oxidizing agent

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

a sulfamic acid compound, or alternatively, includes a reaction product of a sulfamic acid compound with a bromine-based oxidizing agent

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

a reverse osmosis membrane treatment means for subjecting the prefiltration-treated water from the prefiltration treatment means to a reverse osmosis membrane treatment

Methodology Applied
Scientific EffectReverse osmosis: Reverse Osmosis

Implementation Method 4

a prefiltration treatment means for removing insoluble components from a water to be treated that contains organic substance

Methodology Applied
Scientific EffectPhysical filtration: Filter (physical)

Data Source

PatentUS10351444B2Filtration treatment system and filtration treatment method
Publication Date: 2019.07.16 ORGANO CORP
  • US10351444B2 patent drawing
  • US10351444B2 patent drawing
  • US10351444B2 patent drawing

AI summary

This filtration treatment system is provided with a membrane filtration device as a prefiltration treatment device for removing insoluble components from the water to be treated containing organic substance, a reverse osmosis membrane treatment device for subjecting the prefiltration-treated water to reverse osmosis membrane treatment, and a chemical agent supply pipe for supplying a chemical agent into the membrane filtration device, wherein the chemical agent contains a sulfamic acid compound, and a bromine-based oxidizing agent or the reaction product of a bromine compound with a chlorine-based oxidizing agent, or, contains the reaction product of a sulfamic acid compound with a bromine-based oxidizing agent or with the reaction product of a bromine compound with a chlorine-based oxidizing agent.