Brown Macroalgae Biorefinery via Solvent Dehydration

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Solution Overview

Problem

The biorefinery of brown macroalgae faces challenges due to seasonal availability, high water content, and energy-intensive drying processes, as well as the loss of valuable components like mannitol during ensiling, leading to inefficient and costly processing and waste generation.

Innovation Solution

The process involves contacting brown macroalgae with an organic solvent system to induce dehydration, reducing moisture content and isolating valuable components like mannitol, allowing for cost-effective and sustainable biorefining of macroalgae throughout the year.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If brown macroalgae are dried to ensure year-round availability, then preservability is improved, but energy consumption increases significantly due to high moisture content (80-85%)

Engineering Contradiction:
ImprovepreservabilityVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The invention changes the parameter of moisture content from 80-85% to below 10% through solvent-induced dehydration, achieving preservability without high energy consumption associated with conventional drying methods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the thermal drying system with a chemical dehydration system using organic solvents, substituting energy-intensive heat treatment with a chemical process that occurs at ambient or moderate temperatures

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Use of energy by moving object

If brown macroalgae are ensiled to reduce energy demand, then energy consumption decreases, but valuable carbohydrates like mannitol are consumed by bacteria, reducing valorizability

Engineering Contradiction:
Improveenergy consumptionVSAvoidmannitol content
Core Design Contradiction:
Use of energy by moving objectVSLoss of substance

Solution Approach 1:

The invention extracts mannitol and other valuable components from the macroalgae using organic solvents before ensiling, removing these substances from the system to prevent their consumption by bacteria during storage

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention performs solvent-induced dehydration and component isolation as a preliminary step before ensiling, preventing the loss of valuable carbohydrates that would otherwise occur during bacterial fermentation in the silo

Inventive Principle:
Principle #10Preliminary action

3Productivity

If conventional biorefining processes are used, then processing can proceed, but large waste streams are generated with diluted valuable components that are economically unviable to isolate

Engineering Contradiction:
Improveprocessing throughputVSAvoidvaluable components in waste streams
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The invention converts the harmful waste streams into valuable resources by using solvent-induced dehydration to concentrate valuable components like mannitol, laminarin, and fucoidan in the liquid phase, making their isolation economically viable

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The invention changes the concentration parameter of valuable components in the liquid phase from diluted to concentrated through solvent-induced dehydration, transforming waste streams into valuable by-products

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reduces processing volumes, increases product concentrations, and enhances preservability, enabling efficient isolation of mannitol and other valuable components, thereby improving the cost-effectiveness and sustainability of seaweed-based biorefineries for fuel and chemical production.

Implementation Method 1

brown macroalgae experience solvent-induced dehydration by contacting the macroalgae with an organic solvent... the structural matrix of the macroalgae shrinks and expels most of the internal moisture, including water-soluble compounds such as mannitol

Methodology Applied
Scientific EffectSolvent-induced dehydration: Liquid-Liquid Extraction

Implementation Method 2

the liquid phase comprising the organic solvent, the expelled moisture and the components dissolved therein

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentUS11230611B2Biorefinery of brown macroalgae
Publication Date: 2022.01.25 NEDERLANDSE ORG VOOR TOEGEPAST NATUURWETENSCHAPPELIJK ONDERZOEK TNO

AI summary

The present invention concerns an improved process for biorefinery of brown macroalgae, which comprises: (a) contacting the brown macroalgae with a solvent system comprising at least 30 wt % organic solvent, to obtain extracted macroalgae as solid residue and a liquor; and (b) biorefining the extracted macroalgae. The inventors have found that the contacting of step (a) results in an efficient and cost-effective dewatering of the macroalgae, wherein up to 95 wt % of the internal moisture of the macroalgae could be lost without the need for energy-consuming drying techniques. As such, the downstream biorefinery of the extracted macroalgae is greatly facilitated.