Back Side Illumination Sensor Dark Current Reduction

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Solution Overview

Problem

Back side illumination CMOS image sensors experience dark current degradation due to plasma-based treatments that trap positive charges in the anti-reflective silicon nitride layer, leading to unwanted light reflection and image quality issues.

Innovation Solution

A conductive, silicon-rich layer containing hydrogenated amorphous silicon or silicon nitride with a high Si/N ratio is introduced above the anti-reflective layer to absorb or evacuate trapped charges before plasma treatments, reducing residual positive charges and dark current.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If plasma-based treatments are used during back side processing to form contact pads and protective layers, then manufacturing capability is improved, but dark current increases due to charge trapping in the anti-reflective layer

Engineering Contradiction:
Improvemanufacturing capabilityVSAvoiddark current
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

A silicon-rich layer is deposited on the back side of the substrate before plasma-based treatments. This preliminary layer serves as a protective barrier that prevents positive charge trapping in the anti-reflective silicon nitride layer during subsequent plasma processing steps, thereby eliminating dark current while allowing the plasma treatments to proceed for contact pad formation and protective layer deposition.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The silicon-rich layer acts as an intermediary between the plasma environment and the anti-reflective silicon nitride layer. It absorbs or blocks the harmful effects of plasma treatment that would otherwise cause charge trapping, allowing the plasma processes to be performed without generating dark current in the underlying anti-reflective layer.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-affected harmful factors

If the anti-reflective silicon nitride layer is made thicker to improve optical performance, then light reflection is reduced, but charge trapping increases leading to higher dark current

Engineering Contradiction:
Improvelight reflectionVSAvoiddark current
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The silicon-rich layer is deposited before plasma treatments to prevent charge trapping in the anti-reflective layer, allowing the anti-reflective layer to be optimized for optical performance without the penalty of increased dark current from plasma-induced charge trapping.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution effectively reduces dark current by up to 50% while maintaining optical transmission, enhancing the performance of back side illumination image sensors.

Implementation Method 1

the plasma charges the silicon oxide-silicon nitride stack triggering a trapping of positive charges (holes) in the anti-reflective silicon nitride layer, holes which will then migrate to the interface with the substrate to create a dark current

Methodology Applied
Scientific EffectCharge trapping and migration:

Implementation Method 2

The silicon nitride layer 4 is an optical anti-reflection layer, the aim of which is notably to effect an adaptation of the optical index between the outside environment and the photodiode in such a way as to avoid reflection of the rays of light

Methodology Applied
Scientific EffectOptical anti-reflection: Anti-Reflective Coating

Data Source

PatentUS9224775B2Back side illumination image sensor with low dark current
Publication Date: 2015.12.29 STMICROELECTRONICS (CROLLES 2) SAS
  • US9224775B2 patent drawing
  • US9224775B2 patent drawing
  • US9224775B2 patent drawing

AI summary

An integrated circuit includes a back side illuminated image sensor formed by a substrate supporting at least one pixel, an interconnect part situated above a front side of the substrate and an anti-reflective layer situated above a back side of the substrate. The anti-reflective layer may be formed of a silicon nitride layer. An additional layer is situated above the anti-reflective layer. The additional layer is formed of one of amorphous silicon nitride or hydrogenated amorphous silicon nitride, in which the ratio of the number of silicon atoms per cubic centimeter to the number of nitrogen atoms per cubic centimeter is greater than 0.7.