Bubble-Column Condenser Staging for Heat Recovery Without Scale

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Solution Overview

Problem

Current seawater desalination technologies are energy- and capital-intensive, with inefficiencies in heat transfer and energy recovery, leading to high costs and environmental concerns due to the formation of hard scale on heat transfer equipment.

Innovation Solution

A multi-stage bubble-column vapor mixture condenser system that uses a carrier-gas stream to facilitate direct contact with a liquid bath, enabling efficient heat transfer and energy recovery through a counterflow arrangement, reducing thermal resistance and energy costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If reverse osmosis (RO) is used for seawater desalination, then the specific electricity requirement can be as low as 4 kWh/m³, but the system requires massive amounts of energy and capital investment

Engineering Contradiction:
Improvespecific electricity requirementVSAvoidtotal energy consumption
Core Design Contradiction:
Use of energy by moving objectVSUse of energy by stationary object

Solution Approach 1:

The desalination process is divided into multiple stages with intermediate heat recovery points. Each stage operates at different pressure and temperature conditions, allowing progressive concentration of brine and recovery of thermal energy at each step, thereby reducing total energy consumption while maintaining low specific electricity requirements

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system changes operating parameters (temperature, pressure, concentration) across different stages of the process. By varying these parameters and recovering energy at each transition point, the system achieves efficient desalination with reduced overall energy and capital requirements compared to single-stage RO

Inventive Principle:
Principle #35Parameter changes

2Reliability

If thermal-energy-based multi-stage flash (MSF) distillation or multi-effect distillation (MED) is used, then desalination can be achieved, but the processes are energy- and capital-intensive

Engineering Contradiction:
Improvedesalination capabilityVSAvoidenergy intensity
Core Design Contradiction:
ReliabilityVSUse of energy by stationary object

Solution Approach 1:

The system incorporates feedback loops where thermal energy from later stages is fed back to earlier stages. This internal heat recovery mechanism reduces external energy input requirements while maintaining reliable desalination capability, addressing both the reliability and energy intensity concerns

Inventive Principle:
Principle #23Feedback

3Productivity

If MSF and MED systems operate at high temperatures, then desalination efficiency improves, but calcium sulphate precipitation forms hard scale on heat transfer equipment

Engineering Contradiction:
Improvedesalination efficiencyVSAvoidhard scale formation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The concentration process is segmented into multiple stages with progressively increasing brine concentration. Each stage operates at optimized temperature and pressure conditions that prevent calcium sulphate saturation, thereby maintaining high desalination efficiency without hard scale formation on heat transfer surfaces

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system dynamically adjusts operating parameters (temperature, pressure, residence time) at each stage to keep calcium sulphate below its precipitation point while maximizing water production. This parameter optimization allows high productivity without the harmful scale formation effect

Inventive Principle:
Principle #35Parameter changes

4Reliability

If a standard indirect contact dehumidifier is used, then the dehumidification function is provided, but thermal resistance from incondensable gases reduces heat transfer rates

Engineering Contradiction:
Improvedehumidification functionVSAvoidheat transfer rate
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The system uses a specially designed heat transfer medium that facilitates direct contact between the vapor mixture and condensing surfaces. This intermediary approach eliminates the thermal resistance barrier created by incondensable gases in indirect contact systems, significantly improving heat transfer rates while maintaining reliable dehumidification

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces the mechanical indirect contact heat transfer system with a direct contact or enhanced heat transfer mechanism. This substitution eliminates the thermal resistance issue inherent in indirect contact dehumidifiers, achieving both high heat transfer rates and reliable dehumidification function

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves a significantly higher heat-transfer coefficient, reducing energy costs and overall system costs by maintaining high energy recovery and minimizing equipment costs, while avoiding the formation of hard scale.

Implementation Method 1

uses a carrier-gas stream to facilitate direct contact with a liquid bath, enabling efficient heat transfer

Methodology Applied
Scientific EffectHeat transfer: Convection

Implementation Method 2

enabling efficient heat transfer and energy recovery through a counterflow arrangement

Methodology Applied
Scientific EffectMass transfer: Diffusion

Implementation Method 3

Bubble-column vapor mixture condenser

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 4

enabling efficient heat transfer and energy recovery

Methodology Applied
Scientific EffectLatent heat transfer: Latent Heat

Implementation Method 5

enabling efficient heat transfer and energy recovery through a counterflow arrangement, reducing thermal resistance

Methodology Applied
Scientific EffectCounterflow heat transfer: Convection

Data Source

PatentEP2758142B9Bubble-column vapor mixture condenser
Publication Date: 2019.11.20 MASSACHUSETTS INST OF TECH
  • EP2758142B9 patent drawingFigure 1~2
  • EP2758142B9 patent drawingFigure 3~4
  • EP2758142B9 patent drawingFigure 5

AI summary

In a bubble-column vapor mixture condenser, a fluid source supplies a carrier-gas stream including a condensable fluid in vapor phase. The condensable fluid in liquid form is contained as a bath in a chamber in each stage of the condenser, and the carrier gas is bubbled through the bath to condense the fluid into the bath. Energy from condensation is recovered to a coolant in a conduit that passes through the liquid in the stages of the condenser. The bubble-column vapor mixture condenser can be used, e.g., in a humidification-dehumidification system for purifying a liquid, such as water.