Bubble-Assisted Phase Separation for CO2 Capture Solutions

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Solution Overview

Problem

Existing CO2 capture technologies face challenges with long static separation times, insufficient continuity, and weak antioxidant performance of phase change absorbents, leading to inefficiencies and high energy consumption.

Innovation Solution

A method and apparatus that utilize bubbles to disturb CO2-containing phase change solutions, forming a non-uniform multiphase system to accelerate separation, enhance capture rate, and improve antioxidant performance by using inert gases like CO2 to remove dissolved oxygen.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional static separation method is used for CO2-containing phase change solution, then the separation process is simple, but the separation time is long and continuity is insufficient

Engineering Contradiction:
Improveseparation efficiencyVSAvoidseparation time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent introduces a dynamic separation mechanism where the separator can move between a first position (connected to absorption tower) and a second position (connected to desorption tower). This dynamic positioning enables continuous operation by allowing one separator to separate phases while another simultaneously transfers liquids, eliminating idle time and improving overall productivity without extending separation duration.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent employs multiple separators operating in sequence with continuous liquid circulation. While one separator performs phase separation, another simultaneously transfers the CO2-rich liquid to the desorption tower and returns CO2-lean liquid to the absorption tower. This continuous cyclic operation eliminates interruptions and maintains constant productive action, resolving the contradiction between separation efficiency and separation time.

Inventive Principle:
Principle #20Continuity of useful action

2Use of energy by moving object

If phase change absorbent is used for CO2 capture, then energy consumption is reduced, but antioxidant performance is weak and amine concentration decreases

Engineering Contradiction:
Improveenergy consumptionVSAvoidantioxidant performance
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent introduces an inert gas (nitrogen or carbon dioxide) into the CO2-rich liquid phase in the desorption tower to create an inert atmosphere. This inert gas environment prevents oxidation reactions by excluding oxygen, thereby maintaining the antioxidant performance and stabilizing the amine concentration of the phase change absorbent while preserving the energy efficiency benefits of phase change capture technology.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Productivity

If CO2-rich liquid is sent to desorption tower for regeneration, then CO2 removal is achieved, but energy consumption increases

Engineering Contradiction:
ImproveCO2 removal efficiencyVSAvoiddesorption energy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent utilizes phase change properties of the absorbent material, which transitions between liquid and vapor phases during the absorption and desorption cycles. This phase transition mechanism enables CO2 removal through physical phase changes rather than requiring high-energy chemical reactions, significantly reducing desorption energy consumption while maintaining high CO2 removal efficiency.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The continuous cyclic operation with multiple separators ensures that CO2-rich liquid is continuously transferred to the desorption tower and regenerated liquid is continuously returned to the absorption tower. This continuous operation optimizes energy utilization by maintaining steady-state conditions and avoiding repeated startup/shutdown energy losses, thereby achieving efficient CO2 removal with reduced energy consumption.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method and apparatus significantly enhance separation efficiency, reduce energy consumption, and extend the lifespan of the CO2-rich liquid phase by maintaining amine concentration, while maintaining stable operation and reducing footprint.

Implementation Method 1

the thrust effect generated by the bubble generator can promote the form of eddy current in the phase separator, which further accelerates the separation of different density solution system

Methodology Applied
Scientific EffectThrust effect:

Implementation Method 2

the thrust effect generated by the bubble generator can promote the form of eddy current in the phase separator, which further accelerates the separation of different density solution system

Methodology Applied
Scientific EffectEddy current: Eddy Currents

Implementation Method 3

accelerates the separation of different density solution system

Methodology Applied
Scientific EffectDensity difference separation: Density Gradient

Implementation Method 4

The gas that generates bubbles is inert gas such as CO2, which can also remove dissolved oxygen in the lower CO2-rich liquid phase and improve the antioxidant performance

Methodology Applied
Scientific EffectGas stripping: Sparging

Data Source

PatentUS20260048359A1Separation method and separation apparatus for co2-containing phase change solution
Publication Date: 2026.02.19 CHINA PETROLEUM & CHEMICAL CORP
  • US20260048359A1 patent drawing

AI summary

A separation method and a separation apparatus for CO2-containing phase change solution are provided. Bubbles are used to disturb CO2-containing phase change solution in order to obtain at least two separated liquid phases. The bubbles and the CO2-containing phase change solution form a non-uniform multiphase system. During the process of bubble uplift, the bubbles combine with the less dense solution system and move upward together to accelerate the separation of different density solution system. At the same time, the thrust effect generated by the bubble generator can promote the form of eddy current in the phase separator, which further accelerates the separation of different density solution system and improves the separation efficiency of the phase change solution.