Quasi-Periodic Buckled OLED for Light Extraction Without Blurring

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Organic light emitting diodes (OLEDs) face inefficiencies in light emission due to refractive index mismatches, leading to light trapping, and existing solutions that improve light output through periodic microstructures complicate the fabrication process.

Innovation Solution

A quasi-periodic buckling structure is introduced on a transparent substrate using a transparent elastomeric layer and metal oxide layer, with fine buckling in the range of 100 to 700 nm and gross buckling in 10 to 20 μm, allowing for improved light extraction without blurring, achieved by depositing a metal layer on the elastomeric layer, which buckles and oxidizes to form a transparent metal oxide layer, and subsequent deposition of an anode and cathode layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a periodic microstructure is imposed into an OLED to improve light output, then light extraction efficiency is improved, but the fabrication process becomes complicated with lithographic and imprinting steps

Engineering Contradiction:
Improvelight extraction efficiencyVSAvoidfabrication process complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent changes the physical state and temperature parameters of the elastomeric substrate during metal deposition. By heating the substrate above the glass transition temperature of the elastomer and then cooling it, the patent induces thermal contraction that creates buckling structures in the metal layer. This parameter-based approach replaces complex lithographic and imprinting processes with a simpler thermal processing method, achieving periodic microstructures through controlled thermal expansion and contraction cycles.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes the glass transition phase transition of the elastomeric substrate. By heating the substrate above its glass transition temperature and then cooling it below, the patent exploits the volume change associated with this phase transition to induce buckling in the deposited metal layer. This phase transition mechanism provides a straightforward pathway to create periodic microstructures without requiring complex fabrication equipment or multiple processing steps.

Inventive Principle:
Principle #36Phase transitions

2Illumination intensity

If a buckled structure is used to extract light, then light output is enhanced, but blurring of light emission occurs

Engineering Contradiction:
Improvelight output intensityVSAvoidlight emission sharpness
Core Design Contradiction:
Illumination intensityVSManufacturing precision

Solution Approach 1:

The patent applies buckling structures only to specific regions of the OLED device rather than uniformly across the entire light-emitting area. By confining the buckled structures to localized zones, the patent enables light extraction enhancement in those regions while preserving sharp, clear light emission from non-buckled regions. This spatial differentiation of structure quality allows simultaneous achievement of enhanced light output and maintained emission sharpness.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent divides the OLED light-emitting surface into distinct segments: regions with buckled structures for light extraction enhancement and regions without buckling for sharp light emission. This segmentation strategy allows different functional zones to coexist on the same device, with each zone optimized for its specific purpose. The segmented approach resolves the contradiction by distributing different structural qualities to different spatial locations.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The quasi-periodic buckling structure enhances light output by 120% relative to flat OLEDs, specifically extracting waveguide modes without blurring the light emission, as demonstrated by increased current efficiency and improved luminance.

Implementation Method 1

the metal layer buckles upon cooling and is oxidized to form a transparent metal oxide layer

Methodology Applied
Scientific EffectThermal contraction: Thermal Contraction

Implementation Method 2

buckling of the metal film results from the compressive stress imposed by the cooling rubber

Methodology Applied
Scientific EffectCompressive stress:

Implementation Method 3

the metal layer buckles upon cooling and is oxidized to form a transparent metal oxide layer

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

The buckled portion increases the light extracted from the OLED relative to one absent the buckling structure

Methodology Applied
Scientific EffectLight extraction:

Implementation Method 5

specifically extracting waveguide modes without blurring the light emission

Methodology Applied
Scientific EffectWaveguide modes: Waveguide

Data Source

PatentUS9923162B2Buckled organic light emitting diode for light extraction without blurring
Publication Date: 2018.03.20 UNIV OF FLORIDA RESEARCH FOUNDATION INC
  • US9923162B2 patent drawing
  • US9923162B2 patent drawing
  • US9923162B2 patent drawing

AI summary

A layered organic light emitting diode (OLED) device comprises a buckled structure over a portion of the light emitting face to provide improved light output relative to flat OLED devices. The buckled structure has a fine buckling and a gross buckling, which are quasi-periodic. Embodiments of the invention are directed to a method of producing the OLED device comprising a buckled structure, where a transparent substrate coated with a transparent elastomeric layer has a thin metal layer deposited on a portion of the elastomeric layer at an elevated temperature. Upon cooling the metal layer buckles with the formation of the quasi-periodic buckling. Subsequently the metal layer is oxidized to a metal oxide layer that retains the buckling. An OLED with a buckling structure over a portion of the emitting face is constructed on the metal oxide layer and retains the buckling of the metal oxide layer.