Bulk Cobalt Contact With Replacement Metal Cap

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Solution Overview

Problem

Conventional metal interconnection wires, such as Copper, face challenges in meeting the demands of miniaturized semiconductor chip designs due to limitations in wire width and pitch, leading to reliability issues and increased resistance, which hinders further miniaturization in semiconductor fabrication.

Innovation Solution

The use of bulk cobalt contacts with a non-cobalt metal cap, formed through a chemical exchange reaction, in the back-end-of-line (BEOL) metallization layers, where the non-cobalt metal cap is integral to the cobalt contact, enhances the reliability and performance of metal interconnections by reducing electro-migration resistance and oxidation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional metal interconnection wires (Copper or Aluminum) are used, then manufacturing process is simple, but wire width and pitch cannot be reduced further due to fabrication processing problems and reliability issues

Engineering Contradiction:
Improvewire width and pitchVSAvoidelectrical current carrying reliability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the material parameter from conventional Copper/Aluminum to Cobalt, enabling smaller wire widths and pitch values. Cobalt's superior material properties allow fabrication at dimensions where conventional metals fail, resolving the contradiction between miniaturization and reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite structure with Cobalt as the core material and an additional metal layer (such as Ruthenium, Rhodium, or Platinum) deposited on the Cobalt surface. This composite approach combines Cobalt's excellent electrical conductivity with the protective properties of the outer metal layer, achieving both miniaturization and reliability.

Inventive Principle:
Principle #40Composite materials

2Productivity

If metal interconnection wires are miniaturized to meet chip design requirements, then feature density increases, but barriers between wires reach design limits and resistance increases

Engineering Contradiction:
Improvefeature densityVSAvoidresistance and electro-migration
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

Changing the material from Copper to Cobalt fundamentally alters the electrical and physical parameters. Cobalt maintains lower resistance and better electro-migration resistance at smaller dimensions, enabling continued feature density improvement without hitting the limitations that constrain conventional metals.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If Cobalt is used instead of Copper, then wire width and pitch can be reduced for miniaturization, but Cobalt is more reactive and prone to oxidation

Engineering Contradiction:
Improvewire width and pitchVSAvoidreactivity and oxidation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent introduces an intermediary metal layer (such as Ruthenium, Rhodium, or Platinum) that deposits on the Cobalt surface. This intermediate layer acts as a protective barrier, preventing direct contact between Cobalt and oxidizing environments, thus eliminating Cobalt's reactivity and oxidation problems while preserving its excellent electrical properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite material system where Cobalt provides excellent electrical conductivity and enables miniaturization, while the outer metal layer (Ruthenium, Rhodium, or Platinum) provides oxidation resistance. This composite structure resolves the contradiction between Cobalt's miniaturization benefits and its reactivity drawbacks.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves the reliability and performance of metal wiring in semiconductor products by using cobalt instead of copper, allowing for smaller wire widths and increased miniaturization while mitigating reactivity and oxidation issues, thus enabling continued advancements in semiconductor design.

Implementation Method 1

perform selective deposition, by a chemical exchange reaction of metal between a non-cobalt metal and Cobalt in the bulk cobalt contact, of a replacement non-cobalt metal cap integrally formed in a top surface region of the bulk cobalt contact

Methodology Applied
Scientific EffectChemical exchange reaction: Redox Reactions

Data Source

PatentUS11251126B2Replacement metal cap by an exchange reaction
Publication Date: 2022.02.15 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US11251126B2 patent drawing
  • US11251126B2 patent drawing
  • US11251126B2 patent drawing

AI summary

Various methods and structures for fabricating BEOL metallization layer including at least one bulk cobalt contact, the at least one bulk cobalt contact including a replacement non-cobalt metal cap integral to the at least one bulk cobalt contact. The method includes performing selective deposition, by a chemical exchange reaction of metal between a non-cobalt metal and Cobalt in the at least one bulk cobalt contact, of the replacement non-cobalt metal cap integrally formed in a top surface region of the bulk cobalt contact.