Bulk Oxide Superconductor Ag Particle Distribution

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional bulk oxide superconductors face challenges in achieving high workability and critical current density, with Ag particle distribution affecting performance under varying external conditions, leading to issues like cracking and reduced mechanical strength.

Innovation Solution

A bulk oxide superconductor with a structure where Ag particles are present only at specific regions, allowing for high workability and critical current density by controlling Ag addition to 5.0 mass % or less during the QMG method, resulting in a structure where Ag particles are either present or absent, optimizing particle distribution for improved mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If Ag is added to improve workability and reduce chipping, then machineability is improved, but Ag particle distribution becomes non-uniform and may cause cracking

Engineering Contradiction:
ImprovemachineabilityVSAvoidcracking resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies local quality by creating distinct regions within the bulk superconductor: a first region with dispersed Ag particles (0.1-5.0 mass%) for improved machineability and reduced chipping, and a second region without Ag particles for high critical current density. This spatial differentiation allows each region to optimize its properties for specific functions, resolving the contradiction between workability and cracking resistance.

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If Ag particles are dispersed throughout the bulk material to improve workability, then machineability is enhanced, but critical current density decreases due to non-uniform distribution

Engineering Contradiction:
ImprovemachineabilityVSAvoidcritical current density
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent segments the bulk superconductor into two distinct regions with different Ag particle distributions. The first region contains dispersed Ag particles for improved workability, while the second region excludes Ag particles to maintain high critical current density. This segmentation allows the material to simultaneously achieve both workability and high critical current density by assigning different compositions to different spatial zones.

Inventive Principle:
Principle #1Segmentation

3Reliability

If Ag is added to reduce contact resistance and enhance electrical properties, then electrical performance is improved, but heat conduction increases which is undesirable for current lead elements

Engineering Contradiction:
Improvecontact resistanceVSAvoidheat conduction
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent applies local quality by concentrating Ag particles (0.1-5.0 mass%) specifically in the first region where they are needed to reduce contact resistance and enhance electrical properties. The second region maintains low Ag content to minimize heat conduction. This localized placement allows the material to achieve low contact resistance where electrical connections are made while maintaining thermal insulation in the bulk material.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables precise working and high magnetic field generation with reduced contact resistance and heat conduction, enhancing the performance of bulk superconducting magnets and current lead elements.

Implementation Method 1

bulk oxide superconductor having a high workability and high critical current density

Methodology Applied
Scientific EffectSuperconductivity: Superconductivity

Implementation Method 2

the melt method such as the QMG (Quench and Melt Growth) method disclosed, in PLTs 1, 2, 3, etc. is a technique which once raises the temperature to a temperature region where the RE2BaCuO5 phases or RE4Ba2Cu2O10 phases and a liquid phase mainly comprised of B—Cu—O can be copresent, cools to right above the peritectic temperature where REBa2Cu3O7-x (123) is formed

Methodology Applied
Scientific EffectPhase transition: Phase Change

Data Source

PatentUS10468580B2Bulk oxide superconductor and method of production of bulk oxide superconductor
Publication Date: 2019.11.05 NIPPON STEEL CORPORATION
  • US10468580B2 patent drawing
  • US10468580B2 patent drawing
  • US10468580B2 patent drawing

AI summary

The present invention has as its problem the provision of a bulk oxide superconductor which has a high workability and high critical current density characteristic regardless of the external conditions and solves the problem by limiting the amount of addition of Ag to 5 mass % or less, using the QMG method to produce a bulk superconductor and thereby obtain a single crystal-like bulk superconductor of a structure with parts where Ag particles are present and parts where Ag particles are not present made to adjoin each other.