C-Axis Aligned Sputtering Target for Reliable Oxide TFT Films

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Solution Overview

Problem

Transistors formed using oxide semiconductors often have lower reliability compared to those formed using amorphous silicon, due to issues with crystal structure and impurity contamination.

Innovation Solution

A sputtering target with an oxide semiconductor having a crystal region where the c-axis is parallel to the normal vector of the top surface is used, along with specific deposition conditions such as low surface temperature, reduced impurity contamination, and optimized substrate temperature and oxygen gas proportion, to deposit an oxide semiconductor film with a crystal region aligned in the same direction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If oxide semiconductor is used as semiconductor thin film material, then alternative to silicon-based materials is achieved, but reliability is inferior to amorphous silicon transistors

Engineering Contradiction:
Improvematerial alternativeVSAvoidtransistor reliability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent changes the crystal structure parameters of the oxide semiconductor by controlling the sputtering process to form a c-axis aligned crystalline structure. This parameter change in crystal orientation resolves the reliability issue while maintaining the material alternative benefit

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates local crystal orientation quality by aligning c-axes perpendicular to the film surface in specific regions. This local quality improvement in crystal structure enhances transistor reliability without requiring complete structural transformation

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If sputtering method is used to deposit oxide semiconductor film, then deposition capability is achieved, but crystal structure alignment and impurity control are challenging

Engineering Contradiction:
Improvedeposition capabilityVSAvoidcrystal structure alignment
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent performs preliminary action by preparing the sputtering target with specific crystal orientation (c-axis perpendicular to target surface) before deposition. This preliminary preparation ensures that the deposited film inherits the aligned crystal structure, achieving manufacturing precision through advance preparation

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces mechanical mixing or physical alignment methods with a field-based sputtering process. By using plasma field to deposit atoms from the oriented target, the crystal structure alignment is transferred to the film without mechanical intervention

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If conventional sputtering target is used, then deposition is achieved, but crystal region alignment with c-axis parallel to normal vector is not obtained

Engineering Contradiction:
Improvedeposition efficiencyVSAvoidcrystal orientation alignment
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent changes the physical parameter of the sputtering target by orienting the crystal structure so that c-axes are parallel to the normal vector of the target surface. This parameter change in target crystal orientation directly produces the desired film alignment while maintaining deposition efficiency

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a highly reliable transistor with reduced defect and impurity levels, improved crystal structure alignment, and increased film density, leading to enhanced semiconductor device performance.

Implementation Method 1

An oxide semiconductor film is deposited by a sputtering method, using a sputtering target including an oxide semiconductor having a crystal region in which the direction of c-axis is parallel to a normal vector of the top surface of the oxide semiconductor

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS12252775B2Sputtering target, method for manufacturing sputtering target, and method for forming thin film
Publication Date: 2025.03.18 SEMICON ENERGY LAB CO LTD
  • US12252775B2 patent drawing
  • US12252775B2 patent drawing
  • US12252775B2 patent drawing

AI summary

There have been cases where transistors formed using oxide semiconductors are inferior in reliability to transistors formed using amorphous silicon. Thus, in the present invention, a semiconductor device including a highly reliable transistor formed using an oxide semiconductor is manufactured. An oxide semiconductor film is deposited by a sputtering method, using a sputtering target including an oxide semiconductor having crystallinity, and in which the direction of the c-axis of a crystal is parallel to a normal vector of the top surface of the oxide semiconductor. The target is formed by mixing raw materials so that its composition ratio can obtain a crystal structure.