C8 Aromatics Isolation via Segmented Fractionation Columns

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Solution Overview

Problem

Current xylene recovery systems using light deadsorbents are inefficient in isolating aromatic C8 hydrocarbons from hydrocarbon streams, requiring additional energy and equipment due to the need for stringent feed purity and higher fractionation column operating pressures.

Innovation Solution

The method involves using two fractionation columns to separate aromatic C8 hydrocarbons into a sidedraw and bottom fraction, with the bottom fraction further fractionated to produce a heavy overhead fraction, which is combined with the sidedraw to efficiently isolate C8 aromatics, allowing for effective separation and downstream processing of selected xylene isomers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If light deadsorbent is used for xylene recovery, then feed purity specifications are relaxed and equipment cost is reduced, but energy consumption increases due to repeated evaporation and lifting during fractionation

Engineering Contradiction:
Improveequipment costVSAvoidenergy consumption
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The fractionation process is divided into two separate columns: a first fractionation column that performs initial separation and removes overhead fractions, and a second fractionation column that completes the separation. This segmentation allows the light deadsorbent to be recovered more efficiently with reduced energy input compared to a single-column system, as each column operates at lower reboiler duties and the deadsorbent requires less repeated evaporation and lifting.

Inventive Principle:
Principle #1Segmentation

2Use of energy by moving object

If heavy deadsorbent is used for xylene recovery, then energy consumption is reduced, but feed purity requirements become more stringent and additional equipment is required

Engineering Contradiction:
Improveenergy consumptionVSAvoidequipment requirements
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The use of heavy deadsorbent is combined with a segmented fractionation approach using two columns. The first column handles initial separation with the heavy deadsorbent, and the second column completes the purification. This segmentation allows the system to maintain lower energy consumption characteristics of heavy deadsorbent systems while simplifying the overall equipment requirements through optimized column design and operation.

Inventive Principle:
Principle #1Segmentation

3Use of energy by moving object

If heavy deadsorbent system is used, then energy consumption is reduced, but operating pressure increases requiring higher pressure ratings for equipment

Engineering Contradiction:
Improveenergy consumptionVSAvoidoperating pressure
Core Design Contradiction:
Use of energy by moving objectVSStress or pressure

Solution Approach 1:

The fractionation process is split into two columns where the first column operates at lower pressure to perform initial separation, and the second column operates at optimized pressure conditions. This segmentation allows the heavy deadsorbent system to maintain its energy efficiency while reducing the operating pressure requirements compared to a single high-pressure column, thereby reducing equipment pressure rating requirements.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the production of selected xylene isomers by efficiently isolating aromatic C8 hydrocarbons, reducing energy costs and equipment requirements, while maintaining product purity and lowering operating pressures.

Implementation Method 1

introducing the hydrocarbon stream to a fractionation column at a feed point; fractionating the hydrocarbon stream in the fractionation column; withdrawing a sidedraw fraction from the fractionation column at a draw point located above the feed point, wherein the sidedraw fraction includes C8 aromatics

Methodology Applied
Scientific EffectFractionation: Fractionation

Data Source

PatentEP3049381B1Apparatuses and methods for isolating c8 aromatics
Publication Date: 2018.08.08 UOP LLC
  • EP3049381B1 patent drawingFigure 1
  • EP3049381B1 patent drawingFigure 2

AI summary

Apparatuses and methods are provided for isolating C8 aromatics from hydrocarbon streams. In one embodiment, a method for separating C8 aromatics from a hydrocarbon stream includes introducing the hydrocarbon stream to a fractionation column at a feed point. Further, the method includes fractionating the hydrocarbon stream in the fractionation column. Also, the method includes withdrawing a sidedraw fraction from the fractionation column at a draw point located above the feed point, wherein the sidedraw fraction includes C8 aromatics.