CAAC-OS Film C-Axis Alignment for Oxygen Defect Reduction

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Solution Overview

Problem

Semiconductor devices face reliability issues due to variations in electric characteristics, particularly in the channel formation region, which are influenced by the stability of the semiconductor film to heat and light, and are exacerbated by defects such as oxygen defects in amorphous oxide semiconductor films.

Innovation Solution

A c-axis aligned crystalline oxide semiconductor (CAAC-OS) film with a crystal part whose c-axis is substantially perpendicular to the surface, containing indium, gallium, and zinc, is used in the channel formation region, which has a longer crystal arrangement length and reduced oxygen defects, enhancing stability and electrical conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If an amorphous oxide semiconductor film is used in the channel formation region, then the manufacturing process is simpler, but the stability to heat and light is poor causing variation in electric characteristics

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidstability to heat and light
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention changes the structural parameter of the oxide semiconductor film from amorphous to c-axis aligned crystalline structure. This parameter change fundamentally improves the stability to heat and light while maintaining the semiconductor functionality, resolving the contradiction between ease of manufacture and reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite structure where the oxide semiconductor film is formed over an aluminum oxide film layer. This composite material approach provides both the semiconductor properties needed for device operation and the thermal stability required for reliable performance, addressing the contradiction between manufacturing simplicity and heat stability.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If an amorphous oxide semiconductor film is used in the channel formation region, then the manufacturing process is simpler, but oxygen defects occur causing variation in electric characteristics

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidcontrol of oxygen defects
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The invention changes the structural parameter from amorphous to c-axis aligned crystalline structure, which inherently reduces oxygen defects. This parameter change improves manufacturing precision regarding defect control while the manufacturing process remains relatively straightforward.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The aluminum oxide film serves as an intermediary layer between the substrate and the oxide semiconductor film. This intermediary layer prevents oxygen deficiency and reduces oxygen defects in the semiconductor film, improving manufacturing precision without significantly complicating the manufacturing process.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Stability of the object's composition

If the crystal arrangement length in the oxide semiconductor film is increased, then the stability to heat and light is improved, but the manufacturing complexity increases

Engineering Contradiction:
Improvestability to heat and lightVSAvoidcrystal structure control
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The invention optimizes the crystal arrangement length parameter to be 1.5 nm or more, which provides sufficient stability to heat and light. By setting a specific threshold value for this parameter, the invention achieves high stability while avoiding the need for excessively complex crystal structure control.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The oxide semiconductor film has a natural tendency to form a c-axis aligned crystalline structure under appropriate deposition conditions. This self-organizing property reduces the manufacturing complexity required to achieve the desired crystal arrangement length, as the structure forms spontaneously rather than requiring complex external control mechanisms.

Inventive Principle:
Principle #25Self-service

4Reliability

If the oxide semiconductor film has high crystal arrangement length, then the electric conductivity is stable, but the manufacturing precision requirements increase

Engineering Contradiction:
Improveelectric conductivity stabilityVSAvoidcrystal orientation control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention changes the crystalline structure parameter to c-axis aligned, which naturally provides stable electric conductivity. This parameter change achieves reliable electrical performance while the manufacturing precision requirements are managed through controlled deposition processes rather than extremely tight tolerances.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention requires c-axis alignment specifically in the region that will form the channel, while other regions of the film can have less stringent requirements. This local quality approach ensures stable electric conductivity where needed without requiring uniform high precision throughout the entire film, reducing overall manufacturing precision requirements.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The CAAC-OS film exhibits high stability to heat and light, reduces oxygen defects, and maintains stable electric conductivity, leading to a highly reliable semiconductor device with minimal variation in electric characteristics.

Implementation Method 1

an oxide semiconductor film which includes a crystal part whose c-axis is substantially perpendicular to a surface of the oxide semiconductor film

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS9478603B2Oxide semiconductor film, transistor, and semiconductor device
Publication Date: 2016.10.25 SEMICON ENERGY LAB CO LTD
  • US9478603B2 patent drawing
  • US9478603B2 patent drawing
  • US9478603B2 patent drawing

AI summary

To provide an oxide semiconductor film which has high stability and does not easily cause variation in electric characteristics of a transistor, a transistor including the oxide semiconductor film in its channel formation region, and a highly reliable semiconductor device including the transistor. The oxide semiconductor film including indium includes a crystal part whose c-axis is substantially perpendicular to a surface of the oxide semiconductor film. In the crystal part, the length of a crystal arrangement part containing indium and oxygen on a plane perpendicular to the c-axis is more than 1.5 nm. Further, the semiconductor device includes the transistor including the oxide semiconductor film in its channel formation region.