Cadmium-Free Quantum Dot Composition for Blue Light Absorption

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Solution Overview

Problem

Cadmium-based quantum dots have inferior photoluminescence properties and stability, posing environmental and health concerns, and existing cadmium-free quantum dots do not provide adequate blue light absorption, which is essential for display devices and color filters.

Innovation Solution

A cadmium-free quantum dot composition comprising a seed, a quantum well, and a shell, where the quantum well has a specific thickness and composition, and a binder polymer with a carboxylic acid group, enhancing blue light absorption without using toxic heavy metals.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If cadmium-based quantum dots are used, then photoluminescence properties are improved, but environmental safety deteriorates

Engineering Contradiction:
Improvephotoluminescence propertiesVSAvoidenvironmental safety
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent removes cadmium from the quantum dot composition entirely, extracting the harmful element while maintaining the functional structure of the quantum dot through alternative materials that do not contain toxic heavy metals

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs composite material structures with multiple layers (seed, quantum well, shell) using non-cadmium semiconductor materials to achieve the desired photoluminescence properties without the environmental hazards of cadmium-based quantum dots

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If cadmium-free quantum dots are used, then environmental safety is improved, but blue light absorption deteriorates

Engineering Contradiction:
Improveenvironmental safetyVSAvoidblue light absorption
Core Design Contradiction:
Object-affected harmful factorsVSUse of energy by moving object

Solution Approach 1:

The patent applies local quality by optimizing the composition and thickness of specific layers (quantum well layer with specific bandgap, shell layer) to enhance blue light absorption in targeted regions of the quantum dot structure, ensuring adequate blue light absorption while maintaining environmental safety

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes material parameters by selecting semiconductor materials with specific bandgap energies and adjusting layer thicknesses to optimize blue light absorption characteristics, transforming the optical properties of cadmium-free quantum dots to match or exceed cadmium-based performance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The quantum dot composition exhibits improved blue light absorption and photoluminescence properties, addressing the limitations of cadmium-free quantum dots and ensuring environmental safety while enhancing display device performance.

Implementation Method 1

Quantum dots may exhibit electroluminescence and photoluminescence properties. Photoluminescence properties of quantum dots may be applied in various fields.

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS11345851B2Composition, patterned film, and electronic device including the same
Publication Date: 2022.05.31 SAMSUNG ELECTRONICS CO LTD
  • US11345851B2 patent drawing
  • US11345851B2 patent drawing
  • US11345851B2 patent drawing

AI summary

A photosensitive composition including a quantum dot; a binder polymer including a carboxylic acid group; a photopolymerizable monomer including a carbon-carbon double bond; and a photoinitiator, a patterned film produced therefrom and a display device including the same. The quantum dot includes a seed including a first semiconductor nanocrystal, a quantum well including a second semiconductor nanocrystal, the quantum well surrounding the seed and a shell disposed on the quantum well, the shell including a third semiconductor nanocrystal and not including cadmium, the second semiconductor nanocrystal has a different composition from each of the first semiconductor nanocrystal and the third semiconductor nanocrystal, and an energy bandgap of the second semiconductor nanocrystal is smaller than an energy bandgap of the first semiconductor nanocrystal and an energy bandgap of the third semiconductor nanocrystal.