Surface-Reacted Calcium Carbonate Antimicrobial Filler

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Solution Overview

Problem

There is a need for methods to produce surface-reacted calcium carbonate that provides additional functionalities, such as antimicrobial activity, is biodegradable, water-resistant, and safe for various applications, while avoiding the health and environmental hazards associated with conventional preservatives.

Innovation Solution

A process involving the treatment of a calcium carbonate material with a H3O+ ion donor and carbon dioxide in an aqueous medium, along with a water-soluble metal cation source, to form a surface-reacted calcium carbonate that can be used as a filler, preservative, or micronutrient delivery agent, tailored for specific applications.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional preservatives are used to prevent microbial contamination, then microbial quality is improved, but health and environmental hazards increase

Engineering Contradiction:
Improvemicrobial qualityVSAvoidhealth and environmental hazards
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent removes harmful preservative substances from the system and replaces them with a physically-based antimicrobial mechanism using surface-reacted calcium carbonate with specific surface properties that inhibit microbial growth without introducing toxic chemicals

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the surface parameters of calcium carbonate through chemical reaction with CO2 and H3O+ ion providers, creating a surface with specific area and reactivity that provides antimicrobial activity without requiring harmful preservative additives

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If surface-reacted calcium carbonate is produced with additional functionalities, then application versatility is improved, but process complexity increases

Engineering Contradiction:
Improveapplication versatilityVSAvoidprocess complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent combines multiple functions (filler, preservative, micronutrient delivery) into a single modified calcium carbonate product by incorporating metal cations during the surface reaction process, eliminating the need for separate treatment steps

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The surface-reacted calcium carbonate is designed to perform multiple functions simultaneously: it acts as a filler, provides antimicrobial protection through surface properties, and can deliver micronutrients through incorporated metal cations, making it universally applicable across different industries

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If metal cations are incorporated into surface-reacted calcium carbonate, then antimicrobial activity is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveantimicrobial activityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent performs preliminary surface modification of calcium carbonate with CO2 and H3O+ ions before incorporating metal cations, creating a reactive surface that facilitates subsequent metal cation incorporation in a single integrated process step

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The surface-reacted calcium carbonate structure itself provides the mechanism for antimicrobial activity through its surface properties and incorporated metal cations, eliminating the need for additional preservative additives or complex multi-step manufacturing processes

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting surface-reacted calcium carbonate exhibits enhanced antimicrobial activity, is biodegradable, and water-resistant, offering long-lasting protection without affecting the properties of the substrate, and can be used in diverse applications including paper, paints, and agricultural products.

Implementation Method 1

treating the calcium carbonate-comprising material with the at least one H3O+ ion donor and carbon dioxide in an aqueous medium to form an aqueous suspension of surface-reacted calcium carbonate

Methodology Applied
Scientific EffectSurface reaction: Chemical Bonding

Implementation Method 2

at least one water-soluble metal cation source is added during said treating step

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS11718759B2Surface-reacted calcium carbonate with functional cations
Publication Date: 2023.08.08 OMYA INT AG

AI summary

A surface-reacted calcium carbonate is described. In embodiments, the surface-reacted calcium carbonate is obtained by a process comprising treating a calcium carbonate-comprising material with at least one H3O+ ion donor, carbon dioxide, and at least one water-soluble metal cation source in an aqueous medium to form an aqueous suspension of surface-reacted calcium carbonate.