Surface-Reacted Calcium Carbonate Granule Production

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Solution Overview

Problem

Conventional granulation processes for surface-reacted calcium carbonate result in unstable and fragile granules that require a high amount of binder, with a significant portion of the binder being lost in the porous structure, leading to poor stability and strength.

Innovation Solution

A method involving the saturation of surface-reacted calcium carbonate with a granulation liquid before adding a binder, under agitation, to reduce binder demand and enhance granule stability, involving steps such as providing surface-reacted calcium carbonate, saturating it with liquid, combining with a binder, and removing the liquid through drying.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional granulation processes are used for surface-reacted calcium carbonate, then granules can be formed, but the granules exhibit low stability and high fragility requiring a high amount of binder

Engineering Contradiction:
Improvegranule stabilityVSAvoidbinder amount
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent applies preliminary action by saturating the porous surface-reacted calcium carbonate particles with liquid binder solution before the granulation process. This pre-saturation ensures that the porous structure is filled with binder, preventing binder loss during granulation and ensuring adequate binder availability for forming strong granules, thereby resolving the contradiction between granule stability and binder quantity required

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent specifically addresses the porous nature of surface-reacted calcium carbonate by utilizing this porosity to advantage. The porous structure is deliberately saturated with binder solution to capture and retain the binder, converting what would be a source of binder loss into a mechanism for binder retention and enhanced granule stability, thus resolving the contradiction between stability and binder consumption

Inventive Principle:
Principle #31Porous materials

2Strength

If a high amount of binder is added to improve granule stability, then granule strength increases, but a significant portion of the binder is lost in the porous structure

Engineering Contradiction:
Improvegranule strengthVSAvoidbinder loss
Core Design Contradiction:
StrengthVSLoss of substance

Solution Approach 1:

The patent turns the porous structure from a source of binder loss into a binder retention mechanism. By controlling the saturation of the porous particles with binder solution before granulation, the binder is captured within the porous structure rather than being lost, thereby maintaining granule strength while minimizing binder loss

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent converts the harmful effect of porosity (which causes binder loss and reduced granule strength) into a beneficial effect. The porous structure, instead of absorbing and wasting binder, is used to retain and distribute binder uniformly, transforming the previously harmful porosity into an advantage that enhances granule strength while reducing overall binder consumption

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of operation

If surface-reacted calcium carbonate is used in granule form, then physical properties like wettability and flowability are improved, but conventional granulation methods result in fragile granules

Engineering Contradiction:
ImproveflowabilityVSAvoidgranule stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-saturating the surface-reacted calcium carbonate particles with binder solution before granulation. This ensures that the particles are adequately coated and bonded from the outset, forming stable granules that maintain the improved flowability and wettability characteristics of surface-reacted calcium carbonate without sacrificing granule stability

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the physical state and distribution parameters of the binder by using a liquid binder solution that is sprayed or mixed with the particles before granulation. This parameter change ensures uniform binder distribution and adequate bonding, forming granules that maintain the desired flowability while achieving the required stability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces granules with improved stability and reduced binder usage, achieving stronger and more consistent granule formation with a wider size range, addressing the fragility and binder loss issues in conventional processes.

Implementation Method 1

saturating the surface-reacted calcium carbonate with one or more liquids

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

due to its porosity, conventional processes do not provide the desired result

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 3

combining the liquid saturated surface-reacted calcium carbonate with the one or more binder under agitation

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 4

removing the liquid from the mixture of step d)

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP2949708B1Method for the production of granules comprising surface-reacted calcium carbonate
Publication Date: 2018.04.04 OMYA INT AG
  • EP2949708B1 patent drawingFigure 1a~1b
  • EP2949708B1 patent drawingFigure 2
  • EP2949708B1 patent drawingFigure 3

AI summary

The present invention relates to a method for the production of granules comprising surface-reacted calcium carbonate by a) providing surface-reacted calcium carbonate, b) saturating the surface-reacted calcium carbonate with one or more liquids; c) providing one or more binder; d) combining the liquid saturated surface-reacted calcium carbonate with the one or more binder under agitation in an agitation device; e) removing the liquid from the mixture of step d); as well as to the granules comprising surface-reacted calcium carbonate obtained by this method.